Ionic Liquids and Water as "Green" Solvents in Organophosphorus Synthesis

被引：19

作者：

Odinets, I. L. ^{[1
]}

Matveeva, E. V. ^{[1
]}

机构：

[1] Russian Acad Sci, AN Nesmeyanov Organoelement Cpds Inst, Moscow 119991, Russia

来源：

CURRENT ORGANIC CHEMISTRY | 2010年 / 14卷 / 12期

关键词：

ALPHA-AMINO PHOSPHONATES; STABILIZED PHOSPHORUS YLIDES; ONE-POT SYNTHESIS; MICROWAVE-ASSISTED SYNTHESIS; WITTIG-HORNER REACTION; AQUEOUS-MEDIA; FACILE SYNTHESIS; ALPHA; BETA-UNSATURATED ESTERS; BETA-AMINOPHOSPHONATES; EFFICIENT SYNTHESIS;

D O I：

10.2174/138527210791330486

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The application of 'green' solvents such as ionic liquids and water is currently being vigorously pursued because of attractive features such as the acceleration of a variety of reactions, their non-toxic nature, the possibility of dissolving a variety of reactants and recyclability in the case of ionic liquids, and cheapness in the case of water. The present review summarizes and critically discusses the data accumulated in recent years on the utilization of these solvents in the field of the synthesis of organophosphorus compounds. Ionic liquids and water were found to be especially suitable for P=O olefinations, synthesis of alpha- and beta-aminophosphonates and some nucleophilic displacement reactions while in some cases they may change the reaction course observed in common organic solvents.

引用

页码：1171 / 1184

页数：14

共 50 条

[21] Current Trends in Green Solvents: Biocompatible Ionic Liquids
Tzani, Andromachi
Karadendrou, Maria-Anna
Kalafateli, Styliani
Kakokefalou, Vasiliki
Detsi, Anastasia
[J]. CRYSTALS, 2022, 12 (12)
[22] Properties of ionic liquids - New solvents for Green chemistry
Anon
[J]. Journal of Research of the National Institute of Standards and Technology, 2002, 107 (01)
[23] Biobased Ionic Liquids: Solvents for a Green Processing Industry?
Hulsbosch, Joris
De Vos, Dirk E.
Binnemans, Koen
Ameloot, Rob
[J]. ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 2016, 4 (06): : 2917 - 2931
[24] Ionic liquids as catalytic green solvents for cracking reactions
Wang, Y
Li, HR
Wang, CM
Jiang, H
[J]. CHEMICAL COMMUNICATIONS, 2004, (17) : 1938 - 1939
[25] Green synthesis of ionic liquids for green chemistry
Ren, RX
[J]. IONIC LIQUIDS AS GREEN SOLVENTS: PROGRESS AND PROSPECTS, 2003, 856 : 70 - 81
[26] Ionic liquids as green solvents for the asymmetric synthesis of cyanohydrins catalysed by VO(salen) complexes
Baleizao, C
Gigante, B
Garcia, H
Corma, A
[J]. GREEN CHEMISTRY, 2002, 4 (03) : 272 - 274
[27] Effect of water and organic solvents on the ionic dissociation of ionic liquids
Li, Wenjing
Zhang, Zhaofu
Han, Buxing
Hu, Suqin
Xie, Ye
Yang, Guanying
[J]. JOURNAL OF PHYSICAL CHEMISTRY B, 2007, 111 (23): : 6452 - 6456
[28] An overview of ionic liquids as solvents in biodiesel synthesis
Fauzi, Ahmad Hafiidz Mohammad
Amin, Nor Aishah Saidina
[J]. RENEWABLE & SUSTAINABLE ENERGY REVIEWS, 2012, 16 (08): : 5770 - 5786
[29] The green synthesis of liranaftate in ionic liquids
Bing, Liu
[J]. Journal of Chemical and Pharmaceutical Research, 2013, 5 (11) : 219 - 222
[30] Ionic Liquids for Green Organic Synthesis
Sowmiah, Subbiah
Cheng, Cathy I.
Chu, Yen-Ho
[J]. CURRENT ORGANIC SYNTHESIS, 2012, 9 (01) : 74 - 95

← 1 2 3 4 5 →