Ionic Liquids and Water as "Green" Solvents in Organophosphorus Synthesis

被引：19

作者：

Odinets, I. L. ^{[1
]}

Matveeva, E. V. ^{[1
]}

机构：

[1] Russian Acad Sci, AN Nesmeyanov Organoelement Cpds Inst, Moscow 119991, Russia

来源：

CURRENT ORGANIC CHEMISTRY | 2010年 / 14卷 / 12期

关键词：

ALPHA-AMINO PHOSPHONATES; STABILIZED PHOSPHORUS YLIDES; ONE-POT SYNTHESIS; MICROWAVE-ASSISTED SYNTHESIS; WITTIG-HORNER REACTION; AQUEOUS-MEDIA; FACILE SYNTHESIS; ALPHA; BETA-UNSATURATED ESTERS; BETA-AMINOPHOSPHONATES; EFFICIENT SYNTHESIS;

D O I：

10.2174/138527210791330486

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The application of 'green' solvents such as ionic liquids and water is currently being vigorously pursued because of attractive features such as the acceleration of a variety of reactions, their non-toxic nature, the possibility of dissolving a variety of reactants and recyclability in the case of ionic liquids, and cheapness in the case of water. The present review summarizes and critically discusses the data accumulated in recent years on the utilization of these solvents in the field of the synthesis of organophosphorus compounds. Ionic liquids and water were found to be especially suitable for P=O olefinations, synthesis of alpha- and beta-aminophosphonates and some nucleophilic displacement reactions while in some cases they may change the reaction course observed in common organic solvents.

引用

页码：1171 / 1184

页数：14

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