Hydrothermal Synthesis and Crystal Structure of Cd(II) Coordination Polymer

被引:0
|
作者
Xing, Jianxin [1 ]
机构
[1] Dezhou Univ, Dept Biol, Dezhou 253023, Peoples R China
关键词
Hydrothermal; Synthesis; Crystal structure; Cd(II); Coordination polymer; COMPLEXES; IMIDAZOLE; LIGANDS; COPPER;
D O I
暂无
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
By hydrothermal method, the compound [Cd(nia)(2)(H(2)O)](n) (nia = nicotinate) was synthesized and its structure was characterized with elemental analysis and X-ray diffractometer. The crystal is orthorhombic, space group Pbca with a = 11.458(s), b = 12.113(2), c = 17.435(3) angstrom, alpha = beta = gamma = 90 degrees, M(r) = 374.62, V = 2419.8(7) angstrom(3), D(c) = 2.057 g/cm(3), F(000) = 1472 and Z = 8. The Cd(II) center adopt a distorted octahedron geometry which is surrounded by 6 coordination atoms from nicotinate and water molecule.
引用
收藏
页码:6619 / 6621
页数:3
相关论文
共 50 条
  • [31] Synthesis and Crystal Structure of a New Cd(II) Coordination Polymer Based on Phthalic Acid and bis(imidazole)
    Gao, Ronghua
    [J]. ASIAN JOURNAL OF CHEMISTRY, 2012, 24 (06) : 2823 - 2824
  • [32] A new heterometallic Cd(II)-Na(I) coordination polymer: Synthesis, crystal structure and photoluminescent property
    You, Li-Mei
    Gao, Jing
    [J]. INORGANIC AND NANO-METAL CHEMISTRY, 2018, 48 (02) : 146 - 149
  • [33] Hydrothermal Synthesis, Crystal Structure and Photoluminescent Property of 2D Layer Coordination Polymer [Cd(mbix)(BIPA)]
    Chen Hong
    Xu Heng
    Liu Guang-Xiang
    Ren Xiao-Ming
    [J]. CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2009, 25 (08) : 1508 - 1512
  • [34] Hydrothermal Synthesis and Crystal Structure of a Novel Binuclear Cd(Ⅱ) Coordination Polymer Based on 1,2-Benzenedicarboxylate and Imidazole
    郭锋
    于伟
    张秀玲
    [J]. Chinese Journal of Structural Chemistry, 2008, (09) : 1123 - 1126
  • [35] Hydrothermal Synthesis, Crystal Structure and Properties of a Novel 3D Metal-Organic Cd(II) Coordination Polymer Based on Helical Units
    Li, Hai-Hua
    Zhang, Peng
    Pu, Jia-Yi
    Zhao, Yu-Ying
    Mei, Chong-Zhen
    [J]. ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 2013, 68 (02): : 127 - 132
  • [36] Hydrothermal Synthesis, Crystal Structure and Properties of a Novel Phosphorus-containing 3D Metal-Organic Cd(II) Coordination Polymer
    Mei, Chong-Zhen
    Hu, Xi-Ying
    Yang, Guang-Rui
    Li, Kai-Hui
    Shan, Wen-Wen
    [J]. ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 2012, 67 (09): : 951 - 955
  • [37] Synthesis, characterisation and crystal structure of a cobalt(II)-hexamethylenetetramine coordination polymer
    Ndifon, Peter T.
    Agwara, Moise O.
    Paboudam, Awawou G.
    Yufanyi, Divine M.
    Ngoune, Jean
    Galindo, Agustin
    Alvarez, Eleuterio
    Mohamadou, Aminou
    [J]. TRANSITION METAL CHEMISTRY, 2009, 34 (07) : 745 - 750
  • [38] Synthesis, characterisation and crystal structure of a cobalt(II)-hexamethylenetetramine coordination polymer
    Peter T. Ndifon
    Moise O. Agwara
    Awawou G. Paboudam
    Divine M. Yufanyi
    Jean Ngoune
    Agustín Galindo
    Eleuterio Álvarez
    Aminou Mohamadou
    [J]. Transition Metal Chemistry, 2009, 34 : 745 - 750
  • [39] Lead(II) arenedisulfonate coordination polymer: Synthesis, crystal structure and properties
    Wang, Li
    Li, GuanFeng
    Liu, Mengjie
    Deng, Dongsheng
    Pei, Yamei
    Wang, Xinyi
    [J]. INORGANIC CHEMISTRY COMMUNICATIONS, 2013, 35 : 192 - 194
  • [40] A Zinc(II) Coordination Polymer with Tetraiodoterephthalate: Synthesis, Crystal Structure, and Luminescence
    Chen, Le
    Chen, Sheng-Chun
    Zhang, Zhi-Hui
    Sun, Fu-An
    Cui, Ai-Jun
    Gao, Hai-Bo
    He, Ming-Yang
    Chen, Qun
    [J]. ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 2012, 67 (08): : 843 - 848