Synthesis and spectral characteristics of ruthenium(III), rhodium(III), and palladium(II) complexes with 2-(3-pyridylmethyliminomethyl)phenol

被引：1
|
作者：
Pekhn'o, V. I. [1 ]
Bon', V. V. [1 ]
Orysyk, S. I. [1 ]
Volkov, S. V. [1 ]
机构：
[1] Natl Acad Sci Ukraine, Vernadsky Inst Gen & Inorgan Chem, UA-03680 Kiev, Ukraine
来源：
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY | 2007年 / 52卷 / 03期
关键词：
D O I：
10.1134/S0036023607030114
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
New Ru(III), Rh(III), and Pd(II) complexes with the ambident ligand 2-(3-pyridylmethyliminomethyl)phenol have been synthesized and characterized by electronic absorption and IR spectroscopy, H-1 NMR, and elemental analysis and electrophoresis methods. The synthesis conditions and the nature of the metal turn out to have an effect on the coordination mode of the ligand in the resulting complexes. The existence of the intramolecular hydrogen bond in the ligand molecule is favorable for its coordination in the molecular form to the complex-forming metal.
引用
收藏
页码：359 / 366
页数：8
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