Ring-Opening 1,3-Dichlorination of Donor-Acceptor Cyclopropanes by Iodobenzene Dichloride

被引：103
|
作者：
Garve, Lennart K. B. [1 ]
Barkawitz, Philip [1 ]
Jones, Peter G. [1 ]
Werz, Daniel B. [1 ]
机构：
[1] Tech Univ Carolo Wilhelmina Braunschweig, Inst Organ Chem, D-38106 Braunschweig, Germany
来源：
ORGANIC LETTERS | 2014年 / 16卷 / 21期
关键词：
SUBSTITUTED CYCLOPROPANES; 3+2 CYCLOADDITION; 1,2-CYCLOPROPANATED SUGARS; ASYMMETRIC-SYNTHESIS; AMINOCYCLOPROPANES; ALDEHYDES; ANNULATION; FURAN; TETRAHYDROFURANS; REARRANGEMENTS;
D O I：
10.1021/ol5029139
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Donor-acceptor cyclopropanes are reacted with iodobenzene dichloride to afford ring-opened products bearing chlorine atoms in the 1- and 3-positions, adjacent to the donor and acceptor groups. A variety of different donors (e.g., alkyl, aryl, N, and O) and acceptor moieties (e.g., ketones, diesters, and dinitriles) are used.
引用
收藏
页码：5804 / 5807
页数：4
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