X-ray powder diffraction study of LiCrP2O7

被引：9

作者：

Ivashkevich, Ludmila S. ^{[1
]}

Selevich, Kirill A. ^{[1
]}

Lesnikovich, Anatoly I. ^{[1
]}

Selevich, Anatoly F. ^{[1
]}

机构：

[1] Belarusian State Univ, Res Inst Physicochem Problems, Minsk 220030, BELARUS

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2007年 / 63卷

关键词：

D O I：

10.1107/S1600536807005752

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The monoclinic crystal structure of lithium chromium(III) diphosphate, LiCrP2O7, isotypic with other members of the series (LiMP2O7)-P-III (M-III = Mn, Fe, V, Mo, Sc and In), was refined from laboratory X-ray powder diffraction data using the Rietveld method. The Cr3+ cation is bonded to six O atoms from five diphosphate anions to form a distorted octahedron. Links between the bent diphosphate anions and the Cr3+ cations result in a three-dimensional network, with tunnels filled by the Li+ cations in a considerably distorted tetrahedral environment of O atoms.

引用

页码：i70 / i72

页数：3

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