Crystal structure of tris (phenylammonium) chloride pentachloroantimonate (III) monohydrate

被引：6

作者：

Chaabouni, S

Savariault, JM

Ben Salah, A

机构：

[1] Fac Sci Sfax, Lab Environm & Sci Mat, Sfax 3018, Tunisia

[2] CNRS, Ctr Elaborat Mat & Etud Struct, F-31055 Toulouse 4, France

来源：

JOURNAL OF CHEMICAL CRYSTALLOGRAPHY | 2004年 / 34卷 / 10期

关键词：

crystal structure; organic antimonate (III) chloride; lone electron pair;

D O I：

10.1023/B:JOCC.0000047639.37886.45

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The tris (phenylammonium) chloride pentachloroantimonate (III) monohydrate salt is triclinic P (1) over bar with the following cell parameters: a=9.4283(3), b=11.4482(3), c=13.1748(3) Angstrom, alpha=113.493(2), beta=90.381(2), gamma=97.331(1)degrees, V=1290.86(6) Angstrom(3), with Z=2 formula units. The structure consists of [C6H5NH3](+) cations, water molecules, Cl- anions, and SbCl5 square pyramids. Hydrogen bonds, established through water molecule, link the anions [SbCl5](2-) and Cl- and make an infinite chain in the [011] direction. Chains are linked together via another hydrogen bond network originating from the ammonium groups. A distortion of the SbCl5 square pyramid can be attributed to the stereo activity of the Sb(III) lone electron pair.

引用

页码：661 / 664

页数：4

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