Reactor design optimization for direct synthesis of hydrogen peroxide

被引：40

作者：

Inoue, Tomoya ^{[1
]}

Kikutani, Yoshikuni ^{[2
]}

Hamakawa, Satoshi ^{[1
]}

Mawatari, Kazuma ^{[2
]}

Mizukami, Fujio ^{[1
]}

Kitamori, Takehiko ^{[2
,3
]}

机构：

[1] Natl Inst Adv Ind Sci & Technol, Res Ctr Compact Chem Proc, Sendai, Miyagi, Japan

[2] KAST, Micro Chem Grp, Kawasaki Ku, Kanagawa, Japan

[3] Univ Tokyo, Grad Sch Engn, Dept Appl Chem, Bunkyo Ku, Tokyo, Japan

来源：

CHEMICAL ENGINEERING JOURNAL | 2010年 / 160卷 / 03期

关键词：

Direct synthesis of hydrogen peroxide from hydrogen and oxygen; Glass-fabricated microreactor; Gas-liquid distribution; MICROFABRICATED MULTIPHASE REACTORS; BED REACTORS; MICROREACTORS; SYSTEMS; OXYGEN; H-2;

D O I：

10.1016/j.cej.2010.02.027

中图分类号：

X [环境科学、安全科学];

学科分类号：

08 ; 0830 ;

摘要：

A glass-fabricated microreactor was applied to the direct synthesis of hydrogen peroxide from hydrogen and oxygen. The direct synthesis reaction is a three-phase reaction, with gas (hydrogen and oxygen), liquid (reaction solution) and solid (catalyst) being involved. We designed an advanced microreactor in which an ideal gas-liquid distribution could be accomplished throughout the catalyst packed bed. We also set up a reaction system that enables the reaction operation at more than 2 MPa over 1 week. With these efforts, more than 3 wt% of hydrogen peroxide was successfully produced using the microreactor technology. (C) 2010 Elsevier B.V. All rights reserved.

引用

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页码：909 / 914

页数：6

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