An electrochemical quartz crystal microbalance study into the deposition of manganese dioxide

被引：34
|
作者：
Owen, Michael P. [1 ]
Lawrance, Geoffrey A. [1 ]
Donne, Scott W. [1 ]
机构：
[1] Univ Newcastle, Discipline Chem, Callaghan, NSW 2308, Australia
来源：
ELECTROCHIMICA ACTA | 2007年 / 52卷 / 14期
基金：
澳大利亚研究理事会;
关键词：
electrochemical quartz crystal microbalance; electrodeposition; electrolytic manganese dioxide; EMD;
D O I：
10.1016/j.electacta.2007.01.012
中图分类号：
O646 [电化学、电解、磁化学];
学科分类号：
081704 ;
摘要：
An electrochemical quartz crystal microbalance (EQCM) has been used to study the effects of electrolyte composition (MnSO4 and H2SO4 concentrations) and anodic current density on the electrodeposition of manganese dioxide. The EQCM, in tandem with the electrode voltage during deposition, has been used to characterize features of the deposition mechanism such as the relative lifetime of the Mn(III) intermediate, the rate of soluble Mn(III) hydrolysis to form MnOOH, and the porosity of the resultant manganese dioxide deposit as a function of crystal nucleation. The connection between the results obtained here and commercial electrodeposition of manganese dioxide were also discussed. (c) 2007 Elsevier Ltd. All rights reserved.
引用
收藏
页码：4630 / 4639
页数：10
相关论文
共 50 条
  • [41] ANALYTICAL APPLICATIONS OF THE ELECTROCHEMICAL QUARTZ CRYSTAL MICROBALANCE
    HILLMAN, AR
    LOVEDAY, DC
    SWANN, MJ
    BRUCKENSTEIN, S
    WILDE, CP
    ACS SYMPOSIUM SERIES, 1992, 487 : 150 - 163
  • [42] ANALYTICAL APPLICATIONS OF THE ELECTROCHEMICAL QUARTZ CRYSTAL MICROBALANCE
    HILLMAN, AR
    LOVEDAY, DC
    SWANN, MJ
    BRUCKENSTEIN, S
    WILDE, CP
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1991, 201 : 166 - PMSE
  • [43] Analysis of crystallization and deposition process using electrochemical-quartz crystal microbalance: A review
    Zhao, Xiaoyu
    Gao, Haoqiang
    Hou, Yongdan
    Gbologah, Lemuel
    Zeng, Xiangdong
    Wang, Yanfei
    JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 2022, 904
  • [44] Electrochemical quartz crystal microbalance study on dissolution of platinum in acid solutions
    Sugawara, Yuu
    Yadav, Amar Prasad
    Nishikata, Atsushi
    Tsuru, Tooru
    ELECTROCHEMISTRY, 2007, 75 (04) : 359 - 365
  • [45] An electrochemical quartz crystal microbalance study of platinum phthalocyanine thin films
    Brown, Richard J. C.
    Brett, Dan J. L.
    Kucernak, Anthony R. J.
    JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 2009, 633 (02) : 339 - 346
  • [46] ELECTROCHEMICAL QUARTZ CRYSTAL MICROBALANCE STUDY OF THE SWELLING OF POLY(VINYLFERROCENE) FILMS
    INZELT, G
    BACSKAI, J
    ELECTROCHIMICA ACTA, 1992, 37 (04) : 647 - 654
  • [47] Electrochemical quartz crystal microbalance study of Si electrodeposition in ionic liquid
    Komadina, J.
    Akiyoshi, T.
    Ishibashi, Y.
    Fukunaka, Y.
    Homma, T.
    ELECTROCHIMICA ACTA, 2013, 100 : 236 - 241
  • [48] Determination of the electrochemical parameters of the electrochemical quartz crystal microbalance.
    Soares, DM
    Tenan, MA
    Wasle, S
    PROCEEDINGS OF THE SYMPOSIUM ON CHEMICAL AND BIOLOGICAL SENSORS AND ANALYTICAL ELECTROCHEMICAL METHODS, 1997, 97 (19): : 788 - 798
  • [49] Electrochemical quartz crystal microbalance study of magnesium porphine electropolymerization process
    O. I. Istakova
    D. V. Konev
    O. A. Goncharova
    A. E. Antipov
    C. H. Devillers
    M. A. Vorotyntsev
    Journal of Solid State Electrochemistry, 2020, 24 : 3191 - 3206
  • [50] Electrochemical quartz crystal microbalance study of magnesium porphine electropolymerization process
    Istakova, O. I.
    Konev, D. V.
    Goncharova, O. A.
    Antipov, A. E.
    Devillers, C. H.
    Vorotyntsev, M. A.
    JOURNAL OF SOLID STATE ELECTROCHEMISTRY, 2020, 24 (11-12) : 3191 - 3206
12345