Luminescence in CeIV polyoxometalate [Ce(W5O18)2]8-: a combined experimental and theoretical study

被引：15
|
作者：
Roy, Lindsay E. [2 ]
Ortiz-Acosta, Denisse [1 ]
Batista, Enrique R. [2 ]
Scott, Brian L. [1 ]
Blair, Michael W. [3 ]
May, Iain [4 ]
Del Sesto, Rico E. [1 ]
Martin, Richard L. [2 ]
机构：
[1] Los Alamos Natl Lab, Mat Phys & Applicat Mat Chem Div, Los Alamos, NM 87545 USA
[2] Los Alamos Natl Lab, Theoret Div T 1, Los Alamos, NM 87545 USA
[3] Los Alamos Natl Lab, Earth Syst Observat Div EES 14, Los Alamos, NM 87545 USA
[4] Los Alamos Natl Lab, Chem Div C IIAC, Los Alamos, NM 87545 USA
来源：
CHEMICAL COMMUNICATIONS | 2010年 / 46卷 / 11期
关键词：
INTRAMOLECULAR ENERGY-TRANSFER;
D O I：
10.1039/b926660g
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Herein we describe the unique luminescent behavior observed in [Ce-IV(W5O18)(2)](8-) clusters and examine the photophysical properties using density functional theory.
引用
收藏
页码：1848 / 1850
页数：3
相关论文
共 50 条
  • [21] Unique Catalytic Performance of the Polyoxometalate [Ti2(OH)2As2W19O67(H2O)]8-: The Role of 5-Coordinated Titanium in H2O2 Activation
    Kholdeeva, Oxana A.
    Donoeva, Baira G.
    Trubitsina, Tatiana A.
    Al-Kadamany, Ghada
    Kortz, Ulrich
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2009, (34) : 5134 - 5141
  • [22] Formation of unsymmetrical polyoxotungstates via transfer of polyoxometalate building blocks.: NMR evidence supports the kinetic stability of the pentatungstate anion, [W5O18]6-, in aqueous solution
    Belai, N
    Sadakane, M
    Pope, MT
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (09) : 2087 - 2088
  • [23] Vibronic Relaxation Pathways in Molecular Spin Qubit Na9[Ho(W5O18)2]•35H2O under Pressure
    Musfeldt, Janice L. L.
    Liu, Zhenxian
    Lopez-Alcala, Diego
    Duan, Yan
    Gaita-Arino, Alejandro
    Baldovi, Jose J.
    Coronado, Eugenio
    MAGNETOCHEMISTRY, 2023, 9 (02)
  • [24] Size-dependent population of trivalent rare earth cations (RE3+) in [(RE)2(H2O)2(SbW9O33)(W5O18)2]15-, and structural characterization of a luthetium-polyoxotungstate complex [Lu3(H2O)4(SbW9O33)2(W5O18)2]21-
    Naruke, H
    Yamase, T
    BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 2002, 75 (06) : 1275 - 1282
  • [25] A lanthanum(III) complex with a lacunary polyoxotungstate:: Na2(NH4)7[La(W5O18)2]•16H2O
    Paz, FAA
    Balula, MSS
    Cavaleiro, AMV
    Klinowski, J
    Nogueira, HIS
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2005, 61 : I28 - I31
  • [26] Elusive Co2O3: A Combined Experimental and Theoretical Study
    Shanbhag, Pavitra N.
    Biswas, Raju K.
    Pati, Swapan K.
    Sundaresan, Athinarayanan
    Rao, Chinthamani Nagesa Ramachandra
    ACS OMEGA, 2020, 5 (45): : 29009 - 29016
  • [27] Sandwich-Type Manganese-Substituted Polyoxometalate, [(α-B-ZnW9O34)2W2Mn2(H2O)2]8-
    Liu, Ying
    Dou, Jianmin
    Wang, Daqi
    Zhang, Xianxi
    Li, Dacheng
    Jia, Yingchun
    JOURNAL OF CHEMICAL CRYSTALLOGRAPHY, 2011, 41 (02) : 186 - 191
  • [28] Spectroscopic Analysis of Vibronic Relaxation Pathways in Molecular Spin Qubit [Ho(W5O18)2]9-: Sparse Spectra Are Key
    Blockmon, Avery L.
    Ullah, Aman
    Hughey, Kendall D.
    Duan, Yan
    O'Neal, Kenneth R.
    Ozerov, Mykhaylo
    Baldovi, Jose J.
    Arago, Juan
    Gaita-Arino, Alejandro
    Coronado, Eugenio
    Musfeldt, Janice L.
    INORGANIC CHEMISTRY, 2021, 60 (18) : 14096 - 14104
  • [29] Novel-type mixed-ligand polyoxotungstolanthanoate, [Ln(BW11O39) (W5O18)]12- (Ln = Ce3+ and Eu3+)
    1600, Chemical Soc of Japan, Tokyo, Japan (73):
  • [30] A Combined Experimental and Theoretical Study of the Ti2 + N2O Reaction
    Marzouk, A.
    Bolvin, H.
    Reinhardt, P.
    Manceron, L.
    Perchard, J. P.
    Tremblay, B.
    Alikhani, M. E.
    JOURNAL OF PHYSICAL CHEMISTRY A, 2014, 118 (03): : 561 - 572
12345