An abnormal reaction of N-(2,4-dinitrophenyl)-L-proline with thionyl chloride

被引：0
|
作者：
Xu, ZB
Guo, ZR [1 ]
机构：
[1] Chinese Acad Med Sci, Inst Mat Med, Beijing 100050, Peoples R China
[2] Peking Union Med Coll, Beijing 100050, Peoples R China
来源：
CHINESE CHEMICAL LETTERS | 2003年 / 14卷 / 02期
关键词：
L-proline; 1-fluoro-2,4-dinitrobenzene(FDNB); N-(2,4-dinitrophenyl)-4-amino-n-butyl aldehyde;
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
N- (2,4-Dinitrophenyl)-4-amino-n-butyl aldehyde 3 was obtained with high yield of 80% when N- (2,4-dinitroplienyl)-L-proline 1 reacted with SOCK at room temperature. However, the anticipated product N- (2,4-dinitroplienyl)-tetrahydropyrrolyl-2- (4-methylthiophenyl) ketone 2 did not be produced. The mechanism was discussed in this article.
引用
收藏
页码：133 / 134
页数：2
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