Synthesis of BaTiO3 nanoparticle/poly(2-hydroxyethyl methacrylate) hybrid nanofibers via electrospinning

被引：19

作者：

Mimura, Ken-ichi ^{[1
]}

Moriya, Makoto ^{[1
]}

Sakamoto, Wataru ^{[1
]}

Yogo, Toshinobu ^{[1
]}

机构：

[1] Nagoya Univ, Div Nanomat Sci, EcoTopia Sci Inst, Chikusa Ku, Nagoya, Aichi 4648603, Japan

来源：

COMPOSITES SCIENCE AND TECHNOLOGY | 2010年 / 70卷 / 03期

关键词：

Nano composite; Nanoparticles; Sol-gel methods; Fibers; Electrospinning; BARIUM-TITANATE;

D O I：

10.1016/j.compscitech.2009.11.026

中图分类号：

TB33 [复合材料];

学科分类号：

摘要：

BaTiO3 nanoparticielpoly(2-hydroxyethyl methacrylate) (PHEMA) hybrid nanofibers were fabricated from an in situ synthesized BaTiO3 nanoparticle/polymer hybrid by electrospinning. The bulk hybrid for nanofibers was synthesized through the in situ hydrolysis of Ba-Ti alkoxide modified with 2-vinyl-oxyethanol and subsequent copolymerization with HEMA monomer. IR and (13C) NMR spectra showed the formation of polymer matrix. The molecular weights of BaTiO3 nanoparticle/PHEMA hybrid for spinning were 1.3 x 10(5) for 20 equiv. PHEMA and 5.7 x 10(5) for 30 equiv. PHEMA. The crystallite size of BaTiO3 particles in the hybrid was 4.5 nm according to the Scherrer equation. The diameter of BaTiO3 nanoparticle/PHEMA hybrid nanofibers ranged from 500 nm to 1 mu m. A field stress-strain curve was observed for the BaTiO3 nanoparticle/PHEMA hybrid nanofiber. (C) 2009 Elsevier Ltd. All rights reserved.

引用

页码：492 / 497

页数：6

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