Excess molar volumes of (octane+1-chlorobutane) at temperatures between 298.15 and 328.15 K and at pressures up to 40 MPa

被引：18
|
作者：
Morávková, L [1 ]
Linek, J [1 ]
机构：
[1] Acad Sci Czech Republ, Inst Chem Proc Fundamentals, E Hala Lab Thermodynam, CR-16502 Prague 6, Czech Republic
来源：
JOURNAL OF CHEMICAL THERMODYNAMICS | 2003年 / 35卷 / 01期
关键词：
octane; 1-chlorobutane; binary mixture; density; excess volume; high pressure; elevated temperature;
D O I：
10.1016/S0021-9614(02)00307-5
中图分类号：
O414.1 [热力学];
学科分类号：
摘要：
The (p, V, T) behaviour of (octane + I-chlorobutane) was measured at the temperatures (298.15, 308.15, 318.15, and 328.15)K and over the pressure range (0.1 to 40 MPa) with an accuracy in density of +/-1 (.) 10(-4) g (.) cm(-3). An apparatus for (p, V-m, T) measurements of liquids and liquid mixtures whose main part is a high-pressure vibrating-tube densimeter working in a static mode was used for the measurements. Excess molar volumes were calculated from the data and fitted to the Redlich-Kister equation. (C) 2003 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码：113 / 121
页数：9
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