Chemistry of macrocyclic tetracarbene complexes: Synthesis, structure, reactivity and catalytic application

被引：15
|
作者：
Mageed, Ahmed Hassoon [1 ]
机构：
[1] Univ Kufa, Dept Chem, Fac Sci, POB 21, Najaf 54001, Iraq
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2019年 / 902卷
关键词：
Macrocyclic ligands; N-heterocyclic carbene; Transition metals; Catalyst; HETEROCYCLIC CARBENE COMPLEXES; TRANSITION-METAL-COMPLEXES; COORDINATION CHEMISTRY; AROMATIC-COMPOUNDS; AMMONIA REDUCTION; BEARING; NHC; (FENO)(7); PORPHYRIN; LIGAND;
D O I：
10.1016/j.jorganchem.2019.120965
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A narrow area of macrocyclic ligands, including N-heterocyclic carbene (NHC) groups and their metal complexes, is reported in the review. This review highlights recent perspectives in the fields of synthesis and structures of mononuclear macrocyclic NHC metal complexes and their catalytic applications. The review covers some transition metals (Cr, Fe, Co, Ni, Rh, Ru, Pd, Pt and Au) and group 13 and 14 metals (Sn, In and Al) with a limited number of macrocyclic tetra-NHC ligands. (C) 2019 Elsevier B.V. All rights reserved.
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页数：23
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