Recent advances in the total synthesis of cyclobutane-containing natural products

被引：155
|
作者：
Li, Jinshan [1 ]
Gao, Kai [1 ]
Bian, Ming [2 ]
Ding, Hanfeng [1 ,3 ]
机构：
[1] Taizhou Univ, Sch Adv Study, Inst Med Nat Prod, Taizhou 318000, Peoples R China
[2] Shanghai Inst Technol, Sch Chem & Environm Engn, 100 Haiquan Rd, Shanghai 201418, Peoples R China
[3] Zhejiang Univ, Dept Chem, Hangzhou 310058, Zhejiang, Peoples R China
来源：
ORGANIC CHEMISTRY FRONTIERS | 2020年 / 7卷 / 01期
基金：
中国国家自然科学基金;
关键词：
ENDIANDRIC ACID CASCADE; STEREOCONTROLLED TOTAL-SYNTHESIS; STEREOSELECTIVE TOTAL-SYNTHESIS; UNPRECEDENTED CARBON SKELETON; PLANT-GROWTH PROMOTERS; ORGANIC-SYNTHESIS; ELECTROCYCLIC REACTIONS; BIOMIMETIC APPROACH; CATALYZED SYNTHESIS; PHEROMONE SYNTHESIS;
D O I：
10.1039/c9qo01178a
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Complex natural products bearing strained cyclobutane subunits, including terpenoids, alkaloids and steroids, not only display fascinating architectures, but also show potent biological activities. Due to their unique structures as critical core skeletons in these molecules, a variety of new strategies for the construction of cyclobutane rings have greatly emerged during the last decade. In this review, we wish to summarize the recent progress in the cyclobutane-containing natural product synthesis with an emphasis on disconnection tactics employed to forge the four-membered rings, aiming to provide a complement to existing reviews.
引用
收藏
页码：136 / 154
页数：19
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