Nonresonant ionization detected IR spectroscopy for the vibrational study in a supersonic jet

被引：74
|
作者：
Omi, T [1 ]
Shitomi, H [1 ]
Sekiya, N [1 ]
Takazawa, K [1 ]
Fujii, M [1 ]
机构：
[1] WASEDA UNIV,GRAD SCH SCI & ENGN,DEPT CHEM,SHINJUKU KU,TOKYO 169,JAPAN
来源：
CHEMICAL PHYSICS LETTERS | 1996年 / 252卷 / 3-4期
关键词：
D O I：
10.1016/0009-2614(96)00152-2
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
A spectroscopic technique for the measurement of the lR transition in a supersonic jet has been developed, This spectroscopy, the nonresonant ionization detected IR spectroscopy (NID-IR), detects the IR transition by selective ionization of the vibrationally excited molecule, Because of the ionization detection, it has high sensitivity. Furthermore, the ionization detection allows one to observe the IR spectrum of a specific molecular species by selecting the mass of the corresponding cation, The advantage of NID-IR spectroscopy has been demonstrated by the observation of TR spectra of phenol, o-fluorophenol, acetylene and 7-azaindole in a supersonic jet, The assignments of cis and trans rotational isomers in o-fluorophenol are also discussed.
引用
收藏
页码：287 / 293
页数：7
相关论文
共 50 条
  • [21] SUPERSONIC JET EXPANSIONS IN ANALYTICAL SPECTROSCOPY
    JOHNSTON, MV
    TRAC-TRENDS IN ANALYTICAL CHEMISTRY, 1984, 3 (02) : 58 - 61
  • [22] DETERMINATION OF THE VIBRATIONAL TEMPERATURE OF OCS IN A SUPERSONIC FREE JET
    WALLRAFF, P
    YAMADA, KMT
    WINNEWISSER, G
    JOURNAL OF MOLECULAR SPECTROSCOPY, 1987, 126 (01) : 78 - 81
  • [23] Ionization detected vibrational spectroscopy of size-selected hydrogen-bonding clusters of phenol
    Mikami, N
    Ebata, T
    Fujii, A
    RESONANCE IONIZATION SPECTROSCOPY 1996 - EIGHTH INTERNATIONAL SYMPOSIUM, 1997, (388): : 237 - 240
  • [24] GLOW-DISCHARGE IONIZATION OF A SEEDED SUPERSONIC JET
    MILLER, GA
    JOURNAL OF PHYSICAL CHEMISTRY, 1992, 96 (15): : 6166 - 6169
  • [25] Supersonic jet-matrix isolation IR spectroscopy and ab initio calculations on the conformations of organic phosphates
    Viswanathan, KS
    Vidya, V
    Sankaran, K
    George, L
    Singh, S
    SECOND INTERNATIONAL CONFERENCE ON LOW TEMPERATURE CHEMISTRY, 1996, : 13 - 14
  • [26] Towards high-resolution laser ionization spectroscopy of the heaviest elements in supersonic gas jet expansion
    R. Ferrer
    A. Barzakh
    B. Bastin
    R. Beerwerth
    M. Block
    P. Creemers
    H. Grawe
    R. de Groote
    P. Delahaye
    X. Fléchard
    S. Franchoo
    S. Fritzsche
    L. P. Gaffney
    L. Ghys
    W. Gins
    C. Granados
    R. Heinke
    L. Hijazi
    M. Huyse
    T. Kron
    Yu. Kudryavtsev
    M. Laatiaoui
    N. Lecesne
    M. Loiselet
    F. Lutton
    I. D. Moore
    Y. Martínez
    E. Mogilevskiy
    P. Naubereit
    J. Piot
    S. Raeder
    S. Rothe
    H. Savajols
    S. Sels
    V. Sonnenschein
    J-C Thomas
    E. Traykov
    C. Van Beveren
    P. Van den Bergh
    P. Van Duppen
    K. Wendt
    A. Zadvornaya
    Nature Communications, 8
  • [27] Structure of saligenin: microwave, UV and IR spectroscopy studies in a supersonic jet combined with quantum chemistry calculations
    Kumar, Sumit
    Singh, Santosh K.
    Calabrese, Camilla
    Maris, Assimo
    Melandri, Sonia
    Das, Aloke
    PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2014, 16 (32) : 17163 - 17171
  • [28] Towards high-resolution laser ionization spectroscopy of the heaviest elements in supersonic gas jet expansion
    Ferrer, R.
    Barzakh, A.
    Bastin, B.
    Beerwerth, R.
    Block, M.
    Creemers, P.
    Grawe, H.
    de Groote, R.
    Delahaye, P.
    Flechard, X.
    Franchoo, S.
    Fritzsche, S.
    Gaffney, L. P.
    Ghys, L.
    Gins, W.
    Granados, C.
    Heinke, R.
    Hijazi, L.
    Huyse, M.
    Kron, T.
    Kudryavtsev, Yu.
    Laatiaoui, M.
    Lecesne, N.
    Loiselet, M.
    Lutton, F.
    Moore, I. D.
    Martinez, Y.
    Mogilevskiy, E.
    Naubereit, P.
    Piot, J.
    Raeder, S.
    Rothe, S.
    Savajols, H.
    Sels, S.
    Sonnenschein, V.
    Thomas, J. -C.
    Traykov, E.
    Van Beveren, C.
    Van den Bergh, P.
    Van Duppen, P.
    Wendt, K.
    Zadvornaya, A.
    NATURE COMMUNICATIONS, 2017, 8
  • [29] VIBRATIONAL SPECTROSCOPY OF VANDERWAALS BONDS - MEASUREMENT OF THE PERPENDICULAR BEND OF ARHCL BY INTRACAVITY FAR INFRARED-LASER SPECTROSCOPY OF A SUPERSONIC JET
    RAY, D
    ROBINSON, RL
    GWO, DH
    SAYKALLY, RJ
    JOURNAL OF CHEMICAL PHYSICS, 1986, 84 (03): : 1171 - 1180
  • [30] Electronic spectroscopy of phthalocyanine in a supersonic jet revisited
    Schlaghaufer, Florian
    Slenczka, Alkwin
    PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2022, 24 (35) : 20921 - 20931
12345