Dilithium 2-aminoterephthalate as a negative electrode material for lithium-ion batteries

被引：10
|
作者：
Renault, Steven [1 ]
Oltean, Viorica Alina [1 ]
Ebadi, Mahsa [1 ]
Edstrom, Kristina [1 ]
Brandell, Daniel [1 ]
机构：
[1] Uppsala Univ, Dept Chem, Angstrom Lab, Box 538, S-75121 Uppsala, Sweden
来源：
SOLID STATE IONICS | 2017年 / 307卷
关键词：
Organic electrode materials; Lithium-ion batteries; Carboxylates; ELECTROCHEMICAL PERFORMANCE; BASIS-SETS; LI; ANODES; NA; BEHAVIORS;
D O I：
10.1016/j.ssi.2017.05.005
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
This work presents the synthesis and characterization of a novel organic Li-battery anode material: dilithium 2-aminoterephthalate (C8H5Li2NO4). When investigated in Li half-cells, the resulting electrodes show stable capacities around ca. 180 mAh g-1 and promising rate capabilities, with battery performance at 500 mA g(-1) and good capacity recovery, despite being an asymmetric compound. DFT calculations indicate a preferential lithiation on carboxylates close to the amino group.
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页码：1 / 5
页数：5
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