A Mossbauer effect and X-ray diffraction investigation of Ti-Sn intermetallic compounds: I. Equilibrium phases

被引：28

作者：

O'Brien, JW

Dunlap, RA ^{[1
]}

Dahn, JR

机构：

[1] Dalhousie Univ, Dept Phys, Halifax, NS B3H 3J5, Canada

[2] Dalhousie Univ, Dept Chem, Halifax, NS B3H 3J5, Canada

来源：

JOURNAL OF ALLOYS AND COMPOUNDS | 2003年 / 353卷 / 1-2期

关键词：

intermetallics; electrode materials; crystal structure; Mossbauer spectroscopy; X-ray diffraction;

D O I：

10.1016/S0925-8388(02)01304-X

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A thorough X-ray diffraction and Mossbauer effect investigation of Ti3Sn, Ti2Sn, Ti5Sn3, Ti6Sn5, and Ti2Sn3 phases in the Ti-Sn binary system has been made. The compounds were verified to have the same crystal structures as those reported in the literature. This work presents the first reported Sn-119 Mossbauer effect spectroscopy data on Ti3Sn, Ti2Sn, Ti5Sn3 and Ti6Sn5. The room temperature center shifts (relative to CaSnO3) and quadrupole splittings have been determined for each of the phases by fitting model spectra to the observed data. These results are important for the interpretation of Mossbauer effect measurements on high capacity Sn-based electrode materials for Li-ion batteries. (C) 2002 Elsevier Science B.V. All rights reserved.

引用

页码：60 / 64

页数：5

共 50 条

[21] In situ X-ray diffraction study of the phase transformation in the non-stoichiometric intermetallic compound Ti3Sn
Ivanova, Olga
Karpets, Myroslav
Yavari, Alain R.
Georgarakis, Konstantinos
Podrezov, Yuriy
JOURNAL OF ALLOYS AND COMPOUNDS, 2014, 582 : 360 - 363
[22] SnO reduction in lithium cells:: study by X-ray absorption, 119Sn Mossbauer spectroscopy and X-ray diffraction
Chouvin, J
Olivier-Fourcade, J
Jumas, JC
Simon, B
Biensan, PH
Madrigal, FJF
Tirado, JL
Vicente, CP
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 2000, 494 (02) : 136 - 146
[23] Mossbauer and X-ray diffraction investigation of nanocrystalline Fe-O alloys
Lileev, AS
Yagodkin, YD
Reissner, M
Steiner, W
JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS, 2003, 258 : 504 - 506
[24] CRYSTALLIZATION AND PRELIMINARY X-RAY DIFFRACTION ANALYSIS OF DISCOIDIN I.
Lobsanov, Yuri D.
Chiu, Jung-Kay
Siu, Chi-Hung
Rini, James M.
ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 1996, 52 : C195 - C195
[25] Mossbauer effect and x-ray diffraction study of Zr-Ti-Cu-Ni-Be bulk metallic glasses
Binczycka, H
Schneider, S
Schaaf, P
JOURNAL OF PHYSICS-CONDENSED MATTER, 2003, 15 (06) : 945 - 955
[26] Characterization of phases formed in the iron carbide process by X-ray diffraction, mossbauer, X-ray photoelectron spectroscopy, and raman spectroscopy analyses
Eungyeul Park
Oleg Ostrovski
Jianqiang Zhang
Stuart Thomson
Russell Howe
Metallurgical and Materials Transactions B, 2001, 32 : 839 - 845
[27] Characterization of phases formed in the iron carbide process by X-ray diffraction, Mossbauer, X-ray photoelectron spectroscopy, and Raman spectroscopy analyses
Park, E
Zhang, JQ
Thomson, S
Ostrovski, O
Howe, R
METALLURGICAL AND MATERIALS TRANSACTIONS B-PROCESS METALLURGY AND MATERIALS PROCESSING SCIENCE, 2001, 32 (05): : 839 - 845
[28] Chemical insertion of SnS2. Characterization by X-ray diffraction, Sn-119 Mossbauer spectroscopy and X-ray absorption
OlivierFourcade, J
Jumas, JC
Womes, M
Lavela, P
Tirado, JL
Morales, J
INTERNATIONAL CONFERENCE ON THE APPLICATIONS OF THE MOSSBAUER EFFECT - ICAME-95, 1996, 50 : 75 - 78
[29] POSSIBILITIES OF X-RAY DIFFRACTION INVESTIGATION OF DIFFERENT PHASES OF SINGLE CONTRACTION OF MUSCLE
RAZUMOVA, LL
LEMAZHIK.BK
MELNIKOV, LA
TSUKERMA.VG
FRANK, GM
BIOPHYSICS-USSR, 1966, 11 (01): : 204 - &
[30] Investigation of the reversible sodiation of Sn foil by ex-situ X-ray diffractometry and Mossbauer effect spectroscopy
Du, Zhijia
Dunlap, R. A.
Obrovac, M. N.
JOURNAL OF ALLOYS AND COMPOUNDS, 2014, 617 : 271 - 276

← 1 2 3 4 5 →