An exploration of corrosion inhibition of mild steel in sulphuric acid solution through experimental study and Monte Carlo simulations

被引:9
|
作者
Boutouil, Aziz [1 ]
Elazhary, Ilhame [1 ]
Laamari, My Rachid [1 ]
El Ayouchia, Hicham Ben [1 ]
Anane, Hafid [1 ]
El Haddad, Mohammadine [1 ]
Stiriba, Salah Eddine [1 ,2 ]
机构
[1] Univ Cadi Ayyad, LCAM, Fac Polydisciplinaire, Safi, Morocco
[2] Univ Valencia, ICMol, Inst Ciencia Mol, Valencia, Spain
关键词
MS; corrosion inhibition; triazole; DFT; Monte Carlo simulations; QUANTUM-CHEMICAL CALCULATIONS; M HCL SOLUTION; CARBON-STEEL; HYDROCHLORIC-ACID; BENZIMIDAZOLE DERIVATIVES; ADSORPTION BEHAVIOR; SCHIFF-BASE; COPPER; PERFORMANCE; RESISTANCE;
D O I
10.1080/01694243.2019.1681741
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
4-[4-(1H-imidazol-1-yl)methyl)-1H-1,2,3-triazol-1-yl]methylbenzophenone (ITBP) and 4[4-(1H-1,2,4-triazol-1-yl)methyl)-1H-1,2,3-triazol-1-yl]methylbenzophenone (TTBP) are synthesized as new heterocyclic compounds of the triazole derivative family and tested successfully as potential inhibitors for MS in 1 M H2SO4 corrosive medium by using gravimetric analysis, electrochemical impedance spectroscopy, potentiodynamic polarization, and energy dispersive X-ray spectroscopy (EDX). Polarization curves show that the tested inhibitors are mixed-type inhibitors. Scanning electron microscopy (SEM) affirmed the existence of an adsorbed film on the steel surface. Monte Carlo simulations were in excellent agreement with the experimental tests.
引用
收藏
页码:549 / 578
页数:30
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