Catalysts for CO2/epoxide ring-opening copolymerization

被引：174
|
作者：
Trott, G. [1 ]
Saini, P. K. [1 ]
Williams, C. K. [1 ]
机构：
[1] Univ London Imperial Coll Sci Technol & Med, Dept Chem, London SW7 2AZ, England
来源：
PHILOSOPHICAL TRANSACTIONS OF THE ROYAL SOCIETY A-MATHEMATICAL PHYSICAL AND ENGINEERING SCIENCES | 2016年 / 374卷 / 2061期
基金：
英国工程与自然科学研究理事会;
关键词：
catalysis; polycarbonate; ring-opening copolymerization; CO2; BETA-DIIMINATE CATALYSTS; METAL CYANIDE COMPLEXES; CARBON-DIOXIDE; PROPYLENE-OXIDE; ALTERNATING COPOLYMERIZATION; CYCLOHEXENE OXIDE; POLY(PROPYLENE CARBONATE); ZINC GLUTARATE; STYRENE OXIDE; ALIPHATIC POLYCARBONATES;
D O I：
10.1098/rsta.2015.0085
中图分类号：
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号：
07 ; 0710 ; 09 ;
摘要：
This article summarizes and reviews recent progress in the development of catalysts for the ring-opening copolymerization of carbon dioxide and epoxides. The copolymerization is an interesting method to add value to carbon dioxide, including from waste sources, and to reduce pollution associated with commodity polymer manufacture. The selection of the catalyst is of critical importance to control the composition, properties and applications of the resultant polymers. This review highlights and exemplifies some key recent findings and hypotheses, in particular using examples drawn from our own research.
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页数：19
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