Bis(1,10-phenanthroline-κ2N,N′)copper(I) chloridobis(1,10-phenanthroline-κ2N,N′) copper(II) hexacosaoxidooctamolybdate(VI) dihydrate

被引：3
|
作者：
Wang, Wen-Ju
Xu, Lin [1 ]
机构：
[1] NE Normal Univ, Dept Chem, Inst Polyoxometallate Sci, Minist Educ, Changchun 130024, Peoples R China
[2] Baicheng Teachers Coll, Dept Chem, Baicheng 137000, Peoples R China
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2007年 / 63卷
关键词：
D O I：
10.1107/S1600536807030450
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The title complex, [(CuCl)-Cl-II(C12H8N2)(2)](2)[Cu-I(C12H8N2)(2)](2)[Mo8O26]center dot 2H(2)O, features a centrosymmetric alpha-type octamolybdate anion, two complex copper counter-cations with Cu in oxidation states +II and +I, and two water molecules of crystallization. The Cu-II ion exhibits a distorted CuN4Cl square-pyramidal coordination, whereas the Cu-I ion is in a distorted tetrahedral CuN4 coordination. The anions, cations and uncoordinated water molecules are linked into a three-dimensional network by O-H center dot center dot center dot O and C-H center dot center dot center dot O hydrogen bonds.
引用
收藏
页码：M1993 / U1844
页数：19
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