Co@NH2-MIL-125(Ti): cobaloxime-derived metal-organic framework-based composite for light-driven H2 production

被引：349

作者：

Nasalevich, M. A. ^{[1
]}

Becker, R. ^{[2
]}

Ramos-Fernandez, E. V. ^{[3
]}

Castellanos, S. ^{[1
]}

Veber, S. L. ^{[4
]}

Fedin, M. V. ^{[4
]}

Kapteijn, F. ^{[1
]}

Reek, J. N. H. ^{[2
]}

van der Vlugt, J. I. ^{[2
]}

Gascon, J. ^{[1
]}

机构：

[1] Delft Univ Technol, NL-2628 BL Delft, Netherlands

[2] Univ Amsterdam, Vant Hoff Inst Mol Sci, NL-1098 XH Amsterdam, Netherlands

[3] Univ Alicante, Inst Univ Mat, Dept Quim Inorgan, Lab Mat Avanzados, E-03080 Alicante, Spain

[4] Int Tomog Ctr, Lab Magnet Resonance, Novosibirsk 630090, Russia

来源：

ENERGY & ENVIRONMENTAL SCIENCE | 2015年 / 8卷 / 01期

关键词：

ELECTRON-PARAMAGNETIC-RES; EFFICIENT HYDROGEN-PRODUCTION; CHARGE SEPARATION; WATER OXIDATION; CARBON-DIOXIDE; REDUCTION; PHOTOCATALYSIS; EVOLUTION; COBALT; CATALYST;

D O I：

10.1039/c4ee02853h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We present a synthetic strategy for the efficient encapsulation of a derivative of a well-defined cobaloxime proton reduction catalyst within a photoresponsive metal-organic framework (NH2-MIL-125(Ti)). The resulting hybrid system Co@MOF is demonstrated to be a robust heterogeneous composite material. Furthermore, Co@MOF is an efficient and fully recyclable noble metal-free catalyst system for light-driven hydrogen evolution from water under visible light illumination.

引用

页码：364 / 375

页数：12

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