Macroporous poly(aromatic amine): Synthesis and film fabrication

被引:11
|
作者
Hill, Jonathan R. [1 ]
Lee, Michael V. [1 ]
Yu, Xiao-Yan [1 ]
Okamoto, Ken [1 ]
Linford, Mathew R. [2 ]
Ariga, Katsuhiko [1 ]
机构
[1] Natl Inst Mat Sci, WPI, Res Ctr Mat Nanoarchitecton MANA, Tsukuba, Ibaraki 3050044, Japan
[2] Brigham Young Univ, Dept Chem & Biochem, Provo, UT 84602 USA
关键词
Polymer; Aromatic amine; Macroporous; Breath figure; Honeycomb film; SELF-ORGANIZED HONEYCOMB; THIN-FILMS; CONDUCTING POLYMER; MESOPOROUS CARBON; INORGANIC OXIDES; POROUS MATERIALS; BREATH FIGURES; BOTTOM-UP; POLYANILINE; COPOLYMERS;
D O I
10.1016/j.colsurfa.2009.07.033
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
New soluble polymers derived from oxidation of 1H,2H-dihyroperimidines and related to poly(1,8-diaminonaphthalene) were synthesized and found to form hexagonally structured macroporous films (macroporous poly(aromatic amine)) derived from the formation of breath figures. The polymers formed well-ordered macroporous films with homogeneous hole sizes between 0.2 and 1 mu m. The polymers also formed other structures including nanofibers, microparticles and hollow membranous objects. (C) 2009 Elsevier B.V. All rights reserved.
引用
收藏
页码:156 / 161
页数:6
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