A novel method for the synthesis of regiospecifically sulfonated porphyrin monomers and dimers

被引：39
|
作者：
Ye, BH [1 ]
Naruta, Y
机构：
[1] Sun Yat Sen Univ, Sch Chem & Chem Engn, Guangzhou 510275, Peoples R China
[2] Kyushu Univ, Inst Fundamental Res Organ Chem, Higashi Ku, Fukuoka 8128581, Japan
来源：
TETRAHEDRON | 2003年 / 59卷 / 20期
关键词：
sulfonation; regiospecific; water-soluble porphyrin; bisporphyrin; trimethylsilyl chlorosulfonate;
D O I：
10.1016/S0040-4020(03)00541-6
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A novel method has been developed to regiospecifically synthesize water-soluble sulfonated porphyrin monomers tetrakis(4'-sulfonatophenyl)porphyrin, tetrakis(3'-sulfonatophenyl)porphyrin, tetrakis(2'-sulfonatophenyl)porphyrin, tetrakis(2,5'-dimethyl-4-sulfonatophenyl)porphyrin, the dimers of 1,2-bis [5,10,15 -tri(2',5'-sulfonatophenyl)porphyrinyl] benzene and 1,2-bis[5,10,15-tri(2',5-dimethyl-4-sulfonatophenyl)porphyrinyl]benzene in high yields through introduction of the trimethylsilyl group on the phenyl rings and reaction with trimethylsilyl chlorosulfonate in CCl4 solvent. (C) 2003 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码：3593 / 3601
页数：9
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