Li5ReN4, a lithium nitridorhenate(VII) with anti fluorite superstructure

被引：0
|
作者：
Chaushli, A
Jacobs, H [1 ]
Weisser, U
Strähle, J
机构：
[1] Univ Dortmund, Lehrstuhl Anorgan Chem 1, Fachbereich Chem, D-44221 Dortmund, Germany
[2] Univ Tubingen, Inst Anorgan Chem, D-7400 Tubingen, Germany
来源：
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2000年 / 626卷 / 09期
关键词：
rhenium; Lithium nitrido rhenate(VII); ternary rhenium(VII) nitride;
D O I：
10.1002/1521-3749(200009)626:9<1909::AID-ZAAC1909>3.0.CO;2-T
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
At 673 K Li3N reacts with Re powder under N-2 to pale yellow, microcrystalline Li5ReN4. The structure determination is based on X-ray powder data: Spacegroup Pmmn (No. 59), Z = 2, a = 6.719(1) Angstrom, b = 6.627(1) Angstrom, c = 4.893(1) Angstrom. The compound crystallizes in an anti-type of a fluorite superstructure. In comparison to the aristo-type - CaF2 - in Li5ReN4 tetrahedral interstices of a ccp nitrogen partial structure are unoccupied. The distribution of these vacancies is related with its orthorhombic distortion. Under aspects of crystal chemistry the tetragonally crystallizing compounds Li6MN4 With M = MO, W result by partially filling up such vacancies.
引用
收藏
页码：1909 / 1914
页数：6
相关论文
共 50 条
  • [41] Nanoporous Li4Ti5O12 Material for the Electrode of Lithium Ion Battery
    Saxena, Sobhit
    Sil, Anjan
    IETE TECHNICAL REVIEW, 2016, 33 (01) : 60 - 63
  • [42] Preparation of Li4Ti5O12 spherical particles for rechargeable lithium batteries
    Kanamura, K
    Chiba, T
    Dokko, K
    JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 2006, 26 (4-5) : 577 - 581
  • [43] Excess lithium storage and charge compensation in nanoscale Li4+xTi5O12
    Wang, Feng
    Wu, Lijun
    Ma, Chao
    Su, Dong
    Zhu, Yimei
    Graetz, Jason
    NANOTECHNOLOGY, 2013, 24 (42)
  • [44] Hydrothermal synthesis of Li4Ti5O12-TiO2 composites and Li4Ti5O12 and their applications in lithium-ion batteries
    Zhang, Erwei
    Zhang, Hailang
    CERAMICS INTERNATIONAL, 2019, 45 (06) : 7419 - 7426
  • [45] Hydrothermal synthesis of Li4-xNaxTi5O12 and Li4-xNaxTi5O12/graphene composites as anode materials for lithium-ion batteries
    Zhu, Jiping
    Zhang, Yangyang
    Zhu, Jie
    Duan, Rui
    Da, Yumin
    2016 THE INTERNATIONAL CONFERENCE ON NANOMATERIAL, SEMICONDUCTOR AND COMPOSITE MATERIALS (ICNSCM 2016), 2016, 65
  • [46] The evolution in electrochemical performance of Li4-XCaxTi5O12 (Ca doped Li4Ti5O12) as anode materials for lithium ion batteries
    Zhang, Ying
    Li, Jun
    Zhang, Fan
    Li, Xiao
    Yuan, Baige
    Xia, Manman
    Zhao, Peng
    Lei, Ruyan
    COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2021, 616
  • [47] Identifying the Chemical Origin of Oxygen Redox Activity in Li-Rich Anti-Fluorite Lithium Iron Oxide by Experimental and Theoretical X-ray Absorption Spectroscopy
    Li, Liang
    Lee, Eungje
    Freeland, John W.
    Fister, Timothy T.
    Thackeray, Michael M.
    Chan, Maria K. Y.
    JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 2019, 10 (04): : 806 - 812
  • [48] EVALUATION OF LI4/3TI5/3O4 AS AN ANODE OF RECHARGEABLE LITHIUM CELL
    KOSHIBA, N
    TAKATA, K
    NAKANISHI, M
    ASAKA, E
    TAKEHARA, Z
    DENKI KAGAKU, 1994, 62 (09): : 870 - 875
  • [49] Topotactic insertion of lithium in the layered structure Li4VO(PO4)2:: The tunnel structure Li5VO(PO4)2
    Kishore, M. Satya
    Pralong, V.
    CaIgnaert, V.
    Malo, S.
    Hebert, S.
    Varadaraju, U. V.
    Raveau, B.
    JOURNAL OF SOLID STATE CHEMISTRY, 2008, 181 (04) : 976 - 982
  • [50] Li4Ti5O12/Li3SbO4/C composite anode for high rate lithium-ion batteries
    Kundu, M.
    Mahanty, S.
    Basu, R. N.
    MATERIALS LETTERS, 2011, 65 (19-20) : 3083 - 3085
12345