Li5ReN4, a lithium nitridorhenate(VII) with anti fluorite superstructure

被引：0

作者：

Chaushli, A

Jacobs, H ^{[1
]}

Weisser, U

Strähle, J

机构：

[1] Univ Dortmund, Lehrstuhl Anorgan Chem 1, Fachbereich Chem, D-44221 Dortmund, Germany

[2] Univ Tubingen, Inst Anorgan Chem, D-7400 Tubingen, Germany

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2000年 / 626卷 / 09期

关键词：

rhenium; Lithium nitrido rhenate(VII); ternary rhenium(VII) nitride;

D O I：

10.1002/1521-3749(200009)626:9<1909::AID-ZAAC1909>3.0.CO;2-T

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

At 673 K Li3N reacts with Re powder under N-2 to pale yellow, microcrystalline Li5ReN4. The structure determination is based on X-ray powder data: Spacegroup Pmmn (No. 59), Z = 2, a = 6.719(1) Angstrom, b = 6.627(1) Angstrom, c = 4.893(1) Angstrom. The compound crystallizes in an anti-type of a fluorite superstructure. In comparison to the aristo-type - CaF2 - in Li5ReN4 tetrahedral interstices of a ccp nitrogen partial structure are unoccupied. The distribution of these vacancies is related with its orthorhombic distortion. Under aspects of crystal chemistry the tetragonally crystallizing compounds Li6MN4 With M = MO, W result by partially filling up such vacancies.

引用

页码：1909 / 1914

页数：6

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