Photochemistry of transition metal p-benzoquinone complexes Photoreduction of the quinone induced by CT excitation

被引：1
|
作者：
Vogler, Arnd [1 ]
机构：
[1] Univ Regensburg, Inst Inorgan Chem, D-93053 Regensburg, Germany
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2014年 / 47卷
关键词：
Photochemistry; p-Quinone; Rhodium(I); Iridium(I); Palladium(II); CHARGE; LIGANDS; PALLADIUM; STATE;
D O I：
10.1016/j.inoche.2014.07.006
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Complexes of Pd(II), Rh(I) and Ir(I) with p-quinone ligands are characterized by metal or ligand (iodide,azide) to quinone CT transitions. CT excitation yields hydroquinones as reduction products. (C) 2014 Elsevier B.V. All rights reserved.
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收藏
页码：42 / 44
页数：3
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