Green synthesis of nickel species in situ modified hollow microsphere TiO2 with enhanced photocatalytic activity

被引：20
|
作者：
Wang, Qi [1 ]
Qin, Zenan [1 ]
Chen, Jie [1 ]
Ren, Baosheng [1 ]
Chen, Qifeng [1 ]
Guo, Yanchuan [2 ]
Cao, Xiaofeng [2 ]
机构：
[1] Univ Jinan, Adv Bldg Mat Engn Res Ctr, Minist Educ, Shandong Prov Key Lab Preparat & Measurement Bldg, 336 Nanxinzhuang West Rd, Jinan 250022, Shandong, Peoples R China
[2] Chinese Acad Sci, TIPC, Key Lab Photochem Convers & Optoelect Mat, 29 Zhongguancun East Rd, Beijing 100190, Peoples R China
来源：
APPLIED SURFACE SCIENCE | 2016年 / 364卷
基金：
中国国家自然科学基金;
关键词：
Green synthesis; Hollow microsphere TiO2; Nickel species modification; High crystallinity; Photocatalytic activitya; EXPOSED; 001; FACETS; CO-DOPED TIO2; TEMPLATE-FREE; FABRICATION; NANOSHEETS; SPHERES; NIO; DEGRADATION; NANOSPHERES; POLLUTANTS;
D O I：
10.1016/j.apsusc.2015.12.033
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
A green template-free solvothermal approach was developed to synthesize hollow microsphere TiO2-modified in situ with nickel species (Ni2+/Ni3+). Oxalic acid played a pivotal role in the formation of hollow architecture, acting as chelating agent, structure-directing reagent, and acidity-modulation reagent, while isopropyl alcohol ensured the formation of spherical structure. The microstructure and composition of the products were characterized with various techniques, and the results showed that the products exhibited not only highly crystallized anatase phase, large specific surface areas, and the mesoporous shell and hollow architecture, but also the coexistence of Ni2+/Ni3+. The unique structure and composition of the photocatalysts resulted in improved UV and visible photocatalytic activity for degradation of Rhodamine-B and 2,4-dichlorophenol. (C) 2015 Elsevier B.V. All rights reserved.
引用
收藏
页码：1 / 8
页数：8
相关论文
共 50 条
  • [41] Direct Synthesis of Anatase TiO2 Nanowires with Enhanced Photocatalytic Activity
    Wu, Hao Bin
    Hng, Huey Hoon
    Lou, Xiong Wen
    ADVANCED MATERIALS, 2012, 24 (19) : 2567 - 2571
  • [42] Facile synthesis of TiO2 hierarchical tubes with enhanced photocatalytic activity
    Zhang, Guanghui
    Zhang, Tianyong
    Li, Bin
    Jiang, Shuang
    Zhang, Xia
    Hai, Li
    Chen, Xingwei
    Song, Mingyue
    Du, Ping
    MATERIALS RESEARCH BULLETIN, 2017, 94 : 247 - 256
  • [43] Synthesis and Physicochemical Properties of Nanostructured TiO2 with Enhanced Photocatalytic Activity
    I. B. Dorosheva
    A. A. Valeeva
    A. A. Rempel
    M. A. Trestsova
    I. A. Utepova
    O. N. Chupakhin
    Inorganic Materials, 2021, 57 : 503 - 510
  • [44] Controlled synthesis of anatase TiO2 octahedra with enhanced photocatalytic activity
    Gai, Ligang
    Mei, Qinghu
    Qin, Xuyang
    Li, Wenpeng
    Jiang, Haihui
    Duan, Xiuquan
    MATERIALS RESEARCH BULLETIN, 2013, 48 (11) : 4469 - 4475
  • [45] Thorny TiO2 nanofibers: Synthesis, enhanced photocatalytic activity and supercapacitance
    Yang, Guorui (yguorui@foxmail.com), 1600, Elsevier Ltd (659):
  • [46] Facile synthesis of TiO2 hollow spheres composed of high percentage of reactive facets for enhanced photocatalytic activity
    Wang, Bin
    Lu, Xiao-Ying
    Yu, Lawrence K.
    Xuan, Jin
    Leung, Michael K. H.
    Guo, Hongfan
    CRYSTENGCOMM, 2014, 16 (43): : 10046 - 10055
  • [47] Synthesis of BiOCl/TiO2 heterostructure composites and their enhanced photocatalytic activity
    Zhang, Guangxin
    Tan, Ye
    Sun, Zhiming
    Zheng, Shuilin
    JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING, 2017, 5 (01): : 1196 - 1204
  • [48] Fabrication of nanostructured hollow TiO2 nanofibers with enhanced photocatalytic activity by coaxial electrospinning
    Chang, Wenkai
    Xu, Fujian
    Mu, Xueyan
    Ji, Lili
    Ma, Guiping
    Nie, Jun
    MATERIALS RESEARCH BULLETIN, 2013, 48 (07) : 2661 - 2668
  • [49] Thorny TiO2 nanofibers: Synthesis, enhanced photocatalytic activity and supercapacitance
    Wang, Jianan
    Yang, Guorui
    Lyu, Wei
    Yan, Wei
    JOURNAL OF ALLOYS AND COMPOUNDS, 2016, 659 : 138 - 145
  • [50] Synthesis and Physicochemical Properties of Nanostructured TiO2 with Enhanced Photocatalytic Activity
    Dorosheva, I. B.
    Valeeva, A. A.
    Rempel, A. A.
    Trestsova, M. A.
    Utepova, I. A.
    Chupakhin, O. N.
    INORGANIC MATERIALS, 2021, 57 (05) : 503 - 510
12345