Recent Developments in Cobalt Catalyzed Carbon-Carbon and Carbon-Heteroatom Bond Formation via C-H Bond Functionalization

被引：90

作者：

Usman, Muhammad ^{[1
]}

Ren, Zhi-Hui ^{[1
]}

Wang, Yao-Yu ^{[1
]}

Guan, Zheng-Hui ^{[1
]}

机构：

[1] Northwest Univ, Dept Chem & Mat Sci, Key Lab Synthet & Nat Funct Mol Chem, Minist Educ, Xian 710127, Peoples R China

来源：

SYNTHESIS-STUTTGART | 2017年 / 49卷 / 07期

基金：

中国国家自然科学基金;

关键词：

cobalt; C-H functionalization; Csp(3)-H functionalization; reaction mechanisms; C-Het bond formation; CROSS-COUPLING REACTIONS; II-RECEPTOR BLOCKERS; ASYMMETRIC ALKENE HYDROGENATION; REDOX-NEUTRAL SYNTHESIS; H/C-O CLEAVAGE; TERMINAL ALKYNES; AROMATIC IMINES; COBALT(III)-CATALYZED ARYL; DIRECT ALKYLATION; ORGANIC-SYNTHESIS;

D O I：

10.1055/s-0036-1589478

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Cobalt catalysts have evolved to be seen as versatile ecocompatible and economical catalysts in organic synthesis in recent years. Cobalt-catalyzed reactions are undoubtedly a classic in synthetic chemistry for the formation of carbon-carbon and carbon-heteroatom bonds. Another important aspect in this field is catalyst variants, such as low-valent and high-valent cobalt catalysts. This review summarizes the recent progress and synthetic utility of low- valent and high-valent cobalt catalysts towards C-H functionalization processes achieving CC, C-O, C-N and C-B bond formation. Mechanistic insight is also discussed, with the goal of serving as a stepping stone for further development in this field. In addition, Csp3-H bond functionalization reactions provide many opportunities for novel synthesis approaches. 1 Introduction 2 Carbon-Carbon Bond Formation 2.1 Csp2-Csp3 Bond Formation 2.2 Csp2-Csp2 Bond Formation 3 Carbon-Nitrogen Bond Formation 4 Csp3-H Bond Functionalization 5 Carbon-Oxygen Bond Formation 6 Carbon-Boron Bond Formation 7 Conclusion

引用

页码：1419 / 1443

页数：25

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