A Photoinduced Cobalt-Catalyzed Synthesis of Pyrroles through in Situ-Generated Acylazirines

被引：40
|
作者：
Pusch, Stefan [1 ]
Kowalczyk, Danuta [1 ]
Opatz, Till [1 ]
机构：
[1] Johannes Gutenberg Univ Mainz, Inst Organ Chem, Duesbergweg 10-14, D-55128 Mainz, Germany
来源：
JOURNAL OF ORGANIC CHEMISTRY | 2016年 / 81卷 / 10期
关键词：
ONE-POT SYNTHESIS; 3,5-DISUBSTITUTED ISOXAZOLES; 1,3-DICARBONYL COMPOUNDS; VINYL AZIDES; 3,5-DIARYLISOXAZOLES; HYDROXYLAMINE; CYCLIZATION; ALDEHYDES; ESTERS;
D O I：
10.1021/acs.joc.6b00511
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Tetrasubstituted pyrroles can be synthesized in a one-pot procedure from isoxazoles. The process includes the photoinduced in situ formation of acylazirines combined with a subsequent cobalt(II)-catalyzed ring expansion with 1,3-diketones.
引用
收藏
页码：4170 / 4178
页数：9
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