Investigation on the nucleation kinetics of antiferroelectric ADP admixtured ferroelectric TGS crystals

被引:6
|
作者
Balu, T.
Rajasekaran, T. R. [1 ]
Rajesh, N. P.
Murugakoothan, P.
机构
[1] Manonmanian Sundaranar Univ, Dept Phys, Tirunelveli 627012, Tamil Nadu, India
[2] SSN Coll Engn, Dept Phys, Madras 603110, Tamil Nadu, India
[3] Pachaiyappas Coll, Dept Phys, Madras 600030, Tamil Nadu, India
关键词
induction period; nucleation parameters; ferroelectrics; ADPTGS;
D O I
10.1016/j.matlet.2007.03.082
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Induction period and interfacial energy have been determined for the aqueous solution growth of ammonium dihydrogen orthophosphate admixtured triglycine sulphate. It is observed that the induction period decreases exponentially with supersaturation and hence the nucleation rate increases with the increase of supersaturation. The solubility of synthesized ADPTGS has been estimated at different temperatures. ADPTGS has a positive temperature coefficient of solubility. Nucleation parameters such as radius of the critical nucleus, number of molecules in the critical nucleus and critical free energy change have also been investigated. (C) 2007 Elsevier B.V. All rights reserved.
引用
收藏
页码:4824 / 4827
页数:4
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