Synthesis and X-ray structure of new cationic allyl complexes of palladium(II) with α-diimine ligands

被引：16
|
作者：
Mechria, A
Rzaigui, M
Bouachir, F [1 ]
机构：
[1] Fac Sci, Chim Coordinat Lab, Monastir 5000, Tunisia
[2] Fac Sci, Lab Chim Mat, Jarzouna 7021, Bizerte, Tunisia
来源：
TETRAHEDRON LETTERS | 2000年 / 41卷 / 37期
关键词：
palladium; cationic allyl complexes; alpha-diimine; methylallyloxyphosphonium salt;
D O I：
10.1016/S0040-4039(00)01096-0
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The cr-diimine ligands Ar-N=C(R)C(R)=N-Ar react with Pd-2(dba)(3) 1 in the presence of methylallyloxyphosphonium hexafluorophosphate [CH2=C(Me)CH2-O-P(NMe2)(3)](+) PF6- 2 to give new cationic allyl complexes of palladium with alpha-diimine ligands 3a and 3b. The molecular structure for 3a was determined by a single-crystal X-ray diffraction, (C) 2000 Published by Elsevier Science Ltd.
引用
收藏
页码：7199 / 7202
页数：4
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