One-pot synthesis of substituted styrenes from vicinal dibromoalkanes and arylboronic acids

被引：3
|
作者：
Tikhonov, A. A.
Vasil'ev, A. A.
Chirskaya, M. V.
Struchkova, M. I.
Merkulova, N. L.
Zlotin, S. G.
机构：
[1] Moscow Chem Lyceum, Moscow 111033, Russia
[2] Russian Acad Sci, ND Zelinsky Inst Organ Chem, Moscow 119991, Russia
[3] ChemBridge Corp, Moscow 119435, Russia
来源：
RUSSIAN CHEMICAL BULLETIN | 2007年 / 56卷 / 01期
关键词：
styrenes; bromoalkenes; boronic acids; cross-coupling; the Suzuki reaction; bromination; dehydrobromination; ionic liquids;
D O I：
10.1007/s11172-007-0020-5
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Dehydrobromination of vicinal dibromoalkanes in systems comprising 1,2-dimethoxy-ethane, N-butyl-N'-methylimidazolium tetrafluoroborate (or tetrabutylammonium bromide), and a base with subsequent palladium-catalyzed cross-coupling of the thus formed bromoalkenes with arylboronic acids furnished substituted styrenes.
引用
收藏
页码：122 / 129
页数：8
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