Modulated self-organization in complex amphiphilic systems

被引:15
|
作者
Fraaije, JGEM [1 ]
Zvelindovsky, AV [1 ]
Sevink, GJA [1 ]
Maurits, NM [1 ]
机构
[1] Univ Groningen, NL-9747 AG Groningen, Netherlands
关键词
block copolymer; morphology; shear; surface; reaction;
D O I
10.1080/08927020008044119
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We discuss novel simulation methods for 3D pattern formation in complex amphiphilic systems. The focus is on the supra-molecular or mesoscopic level. The building blocks consist of sequences of dissimilar monomers. connected in copolymer chain molecules. Internal factors such as composition and architecture of the polymers. but also external factors such as applied shear. embedded reactions and level of confinement control the self-organization phenomena. Specific examples include dynamical pattern formation in polymer surfactant solution, reactive polymer blends and surface directed structure formation in block copolymer liquids. The approach lives in a twilight zone between scientific disciplines. The ambitious goal is the invention of methods For the rational design of truly complex bio-mimicking materials, in which we combine principles from chemical engineering, physics, chemistry and biology. The keyword is self-organization. of course. But do not be mistaken: autonomous self-organization leads to trouble, modulated self-organization leads to beauty.
引用
收藏
页码:131 / 144
页数:14
相关论文
共 50 条
  • [41] SELF-ORGANIZATION OF SUBSTITUTED AZACROWNS BASED ON THEIR DISCOID AND AMPHIPHILIC NATURE
    MERTESDORF, C
    RINGSDORF, H
    LIQUID CRYSTALS, 1989, 5 (06) : 1757 - 1772
  • [42] Self-Organization in Solutions of Stiff-Chain Amphiphilic Macromolecules
    Vasilevskaya, V. V.
    Markov, V. A.
    ten Brinke, G.
    Khokhlov, A. R.
    MACROMOLECULES, 2008, 41 (20) : 7722 - 7728
  • [43] Intramolecular self-organization in amphiphilic polysulfonates bearing bulky hydrophobes
    Shikata, T
    Mizusaki, M
    Morishima, Y
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1996, 212 : 138 - POLY
  • [44] Nanoreactors based on amphiphilic uracilophanes: Self-organization and reactivity study
    Zakharova, Lucia Ya.
    Semenov, Vyacheslav E.
    Voronin, Mikhail A.
    Valeeva, Farida G.
    Ibragimova, Alsu R.
    Giniatullin, Rashid Kh.
    Chernova, Alla V.
    Kharlamov, Sergey V.
    Kudryavtseva, Lyudmila A.
    Latypov, Shamil K.
    Reznik, Vladimir S.
    Konovalov, Alexander I.
    JOURNAL OF PHYSICAL CHEMISTRY B, 2007, 111 (51): : 14152 - 14162
  • [45] SELF-ORGANIZATION OF AMPHIPHILIC MOLECULES - MICELLES AND MICRO-PHASES
    EICKE, HF
    CHIMIA, 1982, 36 (06) : 241 - 246
  • [46] Dendron-Mediated Self-Assembly, Disassembly, and Self-Organization of Complex Systems
    Rosen, Brad M.
    Wilson, Christopher J.
    Wilson, Daniela A.
    Peterca, Mihai
    Imam, Mohammad R.
    Percec, Virgil
    CHEMICAL REVIEWS, 2009, 109 (11) : 6275 - 6540
  • [47] SELF-ORGANIZATION IN HIERARCHICALLY ORGANIZED SYSTEMS
    AUGER, PM
    SYSTEMS RESEARCH, 1990, 7 (04): : 221 - 236
  • [48] Self-organization in systems of treadmilling filaments
    Doubrovinski, K.
    Kruse, K.
    EUROPEAN PHYSICAL JOURNAL E, 2010, 31 (01): : 95 - 104
  • [49] Self-Organization in Mobile Networking Systems
    Choi, Hyun-Ho
    Kwon, Seok-Chul
    Ko, Youngwook
    Lee, Jung-Ryun
    MOBILE INFORMATION SYSTEMS, 2016, 2016
  • [50] Learning and Self-organization for Spatiotemporal Systems
    Runkler, Thomas A.
    Sollacher, Rudolf
    Szabo, Andrei
    KUNSTLICHE INTELLIGENZ, 2012, 26 (03): : 269 - 274