A new coupling reaction for the synthesis of ruthenium half-sandwich complexes with sterically demanding cyclopentadienyl ligands

被引：18

作者：

Gauthier, Sebastien ^{[1
]}

Solari, Euro ^{[1
]}

Dutta, Barnali ^{[1
]}

Scopelliti, Rosario ^{[1
]}

Severin, Kay ^{[1
]}

机构：

[1] Ecole Polytech Fed Lausanne, Inst Sci & Ingn Chim, Lausanne, Switzerland

来源：

CHEMICAL COMMUNICATIONS | 2007年 / 18期

关键词：

D O I：

10.1039/b618712a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of RuCl3(solv.)(n) with tert-butylacetylene in methanol or ethanol leads to the formation of chloro-bridged half-sandwich complexes with sterically demanding cyclopentadienyl ligands, which are of high interest as starting materials for the synthesis of novel Ru catalysts.

引用

页码：1837 / 1839

页数：3

共 50 条

[1] Ruthenium half-sandwich complexes with sterically demanding cyclopentadienyl Ligands
Dutta, Barnali
Solari, Euro
Gauthier, Sebastien
Scopelliti, Rosario
Severin, Kay
[J]. ORGANOMETALLICS, 2007, 26 (19) : 4791 - 4799
[2] Cationic half-sandwich ruthenium(II) complexes with cyclopentadienyl-phosphine ligands
Doppiu, A
Englert, U
Salzer, A
[J]. INORGANICA CHIMICA ACTA, 2003, 350 : 435 - 441
[3] Half-sandwich ruthenium complexes of pentafluorobenzenethiolato ligands
Shawakfeh, Khaled
El-khateeb, Mohammad
Taher, Deeb
Goerls, Helmar
Weigand, Wolfgang
[J]. TRANSITION METAL CHEMISTRY, 2008, 33 (03) : 387 - 391
[4] Half-sandwich ruthenium complexes of pentafluorobenzenethiolato ligands
Khaled Shawakfeh
Mohammad El-khateeb
Deeb Taher
Helmar Görls
Wolfgang Weigand
[J]. Transition Metal Chemistry, 2008, 33 : 387 - 391
[5] ARENE AND CYCLOPENTADIENYL HALF-SANDWICH COMPLEXES OF RUTHENIUM WITH OXIMATES, CARBOXYLATES, IMINES AND AZAVINYLIDENES AS LIGANDS
WERNER, H
DANIEL, T
KNAUP, W
NURNBERG, O
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1993, 462 (1-2) : 309 - 318
[6] Synthesis of new half-sandwich ruthenium(II) complexes bearing alkenyl- and alkynylphosphane ligands
Díez, J
Gamasa, MP
Gimeno, J
Lastra, E
Villar, A
[J]. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2006, (01) : 78 - 87
[7] Half-Sandwich Ruthenium Complexes of Heterocyclic-Dithiocarboxylato Ligands
El-Khateeb, Mohammad
Al-Noaimi, Mousa
Harb, Mohammad
Goerls, Helmar
Weigand, Wolfgang
[J]. JORDAN JOURNAL OF CHEMISTRY, 2008, 3 (02) : 147 - 153
[8] Ruthenocene complexes containing sterically demanding cyclopentadienyl ligands
Schumann, H
Stenz, S
Mühle, SH
Dechert, S
[J]. ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 2003, 58 (06): : 514 - 520
[9] SYNTHESIS, CHARACTERIZATION, AND REACTION CHEMISTRY OF CHIRAL HALF-SANDWICH RUTHENIUM PHOSPHAALLYL COMPLEXES
JI, HL
NELSON, JH
DECIAN, A
FISCHER, J
SOLUJIC, L
MILOSAVLJEVIC, EB
[J]. ORGANOMETALLICS, 1992, 11 (01) : 401 - 411
[10] A new route to cationic half-sandwich ruthenium(II) complexes with chiral cyclopentadienylphosphane ligands
Doppiu, A
Salzer, A
[J]. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2004, (11) : 2244 - 2252

← 1 2 3 4 5 →