Half-sandwich ruthenium complexes of pentafluorobenzenethiolato ligands

被引：5

作者：

Shawakfeh, Khaled ^{[1
]}

El-khateeb, Mohammad ^{[1
]}

Taher, Deeb ^{[2
]}

Goerls, Helmar ^{[3
]}

Weigand, Wolfgang ^{[3
]}

机构：

[1] Jordan Univ Sci & Technol, Dept Chem, Irbid 22110, Jordan

[2] Tafila Tech Univ, Dept Chem, Tafila 61110, Jordan

[3] Univ Jena, Inst Anorgan & Analyt Chem, D-07743 Jena, Germany

来源：

TRANSITION METAL CHEMISTRY | 2008年 / 33卷 / 03期

关键词：

D O I：

10.1007/s11243-008-9059-x

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A synthetic study of ruthenium complexes containing pentafluorobenzenethiolato ligand is presented. The bis(triphenylphosphine) complex CpRu(PPh3)(2)SC6F5 (1) is prepared from CpRu(PPh3)(2)Cl and C6F5S- in high yield. This complex is readily reacted with CO gas to give the mixed carbonyl-phosphine complex CpRu(PPh3)(CO)SC6F5 (2) and with NOBF4 at room temperature to give [CpRu(PPh3)-(NO)SC6F5]BF4 (3). The one-pot reaction of CpRu(PPh3)(2)Cl, dppa ligands, and C6F5S- produces CpRu(dppa)SC6F5 [dppa = bis(diphenylphosphino) methane: dppm (4); bis (diphenylphosphino) ethane: dppe (5)]. Complexes (1)-(5) have been characterized by spectroscopic techniques (i.r., H-1-n.m.r., P-31-n.m.r.) and by elemental analysis. The X-ray structural analysis of (5) is reported.

引用

页码：387 / 391

页数：5

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