Crystal structure of nitrate tris(4-allylthiosemicarbazide)-chromium(III) hydrate

被引：1

作者：

Chumakov, Yu. M. ^{[1
,3
]}

Petrenko, P. A. ^{[1
]}

Graur, V. O. ^{[2
]}

Tsapkov, V. I. ^{[2
]}

Gulea, A. P. ^{[2
]}

机构：

[1] Moldavian Acad Sci, Inst Appl Phys, Kishinev, Moldova

[2] Moldova State Univ, Kishinev, Moldova

[3] Gebze Inst Technol, Cayirova, Kocaeli, Turkey

来源：

JOURNAL OF STRUCTURAL CHEMISTRY | 2016年 / 57卷 / 01期

关键词：

single crystal X-ray diffraction analysis; chromium coordination compounds; 4-allylthiosemicarbazide; COMPLEXES; THIOSEMICARBAZONE; DATABASE;

D O I：

10.1134/S0022476616010261

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The crystal structure of nitrate tris(4-allylthiosemicarbazide)chromium(III) hydrate [CrL3](NO3)(3)(H2O)(1.05) (I), where L is 4-allylthiosemicarbazide, is determined. The asymmetric unit of the cell of the crystal structure of I contains a complex of a chromium ion with three bidentate coordinated molecules L. The outer coordination sphere of the central atom contains a disordered water molecule and three nitrate ions. The coordination polyhedron of the chromium atom in complex I is an octahedron. In the crystal, the complexes of the compound under study are joined with each other by the outer-sphere nitrato groups into a three-dimensional branched net of hydrogen bonds.

引用

页码：202 / 205

页数：4

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