Synthesis of Conjugated Fluorene-alt-thiophene Polymers with Pendant Perylenediimide Units

被引:7
|
作者
Gomez, Rafael [1 ]
Seoane, Carlos [1 ]
Segura, Jose L. [1 ]
机构
[1] Univ Complutense Madrid, Fac Quim, Dept Quim Organ, E-28040 Madrid, Spain
来源
JOURNAL OF ORGANIC CHEMISTRY | 2010年 / 75卷 / 15期
关键词
PHOTOINDUCED ELECTRON-TRANSFER; DOUBLE-CABLE POLYMERS; ENERGY-TRANSFER; PHOTOPHYSICAL PROPERTIES; CHEMICAL SENSORS; FLUORESCENT DYES; BUILDING-BLOCKS; CHARGE-TRANSFER; ACCEPTOR; POLYTHIOPHENE;
D O I
10.1021/jo100816j
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
In this article we present the synthesis, characterization, electrochemical, optical, and preliminary photophysical investigation of two novel poly(fluorene-alt-thiophene) conjugated polymers endowed with pendant perylenediimide electron acceptor units. We show a route to the synthesis of easily functionalizable monomers paving the way to the preparation of a variety of functionalized polymers with different properties and applications and reflecting the versatility of this synthetic methodology.
引用
收藏
页码:5099 / 5108
页数:10
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