Synthesis of Conjugated Fluorene-alt-thiophene Polymers with Pendant Perylenediimide Units

被引：7
|
作者：
Gomez, Rafael [1 ]
Seoane, Carlos [1 ]
Segura, Jose L. [1 ]
机构：
[1] Univ Complutense Madrid, Fac Quim, Dept Quim Organ, E-28040 Madrid, Spain
来源：
JOURNAL OF ORGANIC CHEMISTRY | 2010年 / 75卷 / 15期
关键词：
PHOTOINDUCED ELECTRON-TRANSFER; DOUBLE-CABLE POLYMERS; ENERGY-TRANSFER; PHOTOPHYSICAL PROPERTIES; CHEMICAL SENSORS; FLUORESCENT DYES; BUILDING-BLOCKS; CHARGE-TRANSFER; ACCEPTOR; POLYTHIOPHENE;
D O I：
10.1021/jo100816j
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
In this article we present the synthesis, characterization, electrochemical, optical, and preliminary photophysical investigation of two novel poly(fluorene-alt-thiophene) conjugated polymers endowed with pendant perylenediimide electron acceptor units. We show a route to the synthesis of easily functionalizable monomers paving the way to the preparation of a variety of functionalized polymers with different properties and applications and reflecting the versatility of this synthetic methodology.
引用
收藏
页码：5099 / 5108
页数：10
相关论文
共 50 条
  • [1] A Double-Cable Poly(fluorene-alt-thiophene) with Bay-Substituted Perylenediimide Pendants: An Efficient Interfacial Material in Bulk-Heterojunction Solar Cells
    Chen, Naiwu
    Lu, Jurong
    Wang, Danbei
    Zheng, Chaoyue
    Wu, Huarui
    Zhang, Hongmei
    Gao, Deqing
    MACROMOLECULES, 2018, 51 (01) : 80 - 90
  • [2] Synthesis and properties of conjugated oligomers containing fluorene, fluorenone, thiophene and cyclopentadithiophenone units
    Jaramillo-Isaza, F
    Turner, ML
    JOURNAL OF MATERIALS CHEMISTRY, 2006, 16 (01) : 83 - 89
  • [3] Synthesis and Photovoltaic Properties of Alternating Conjugated Polymers Derived from Thiophene-Benzothiadiazole Block and Fluorene/Indenofluorene Units
    Li, Jianfeng
    Tong, Junfeng
    Zhang, Peng
    Yang, Chunyan
    Chen, Dejia
    Zhu, Yuancheng
    Xia, Yangjun
    Fan, Duowang
    BULLETIN OF THE KOREAN CHEMICAL SOCIETY, 2014, 35 (02) : 505 - 512
  • [4] New thiophene-based donoracceptor conjugated polymers carrying fluorene or cyanovinylene units: Synthesis, characterization, and electroluminescent properties
    Murali, Maluvadi G.
    Dalimba, Udayakumar
    Yadav, Vandana
    Srivastava, Ritu
    POLYMER ENGINEERING AND SCIENCE, 2013, 53 (06): : 1161 - 1170
  • [5] Spectroelectrochemical Study of Electron and Energy Transfer in Poly(fluorene-alt-phenylene) with Perylenediimide Pendant Groups
    Montilla, F.
    Esquembre, R.
    Gomez, R.
    Blanco, R.
    Segura, J. L.
    JOURNAL OF PHYSICAL CHEMISTRY C, 2008, 112 (42): : 16668 - 16674
  • [6] Highly emissive fluorene and thiophene based π-conjugated A-alt-B copolymers: Synthesis, characterization and electroluminescence properties
    Islam, Sk Najmul
    Gogurla, Narendar
    Giri, Dipanjan
    Ray, Samit K.
    Patra, Sanjib K.
    JOURNAL OF LUMINESCENCE, 2019, 208 : 509 - 518
  • [7] Synthesis and Characterization of Fluorene-Based Conjugated Polymers Containing Thiophene Derivatives in Main Chain
    Lee, Sang Kyu
    Jung, Young Kwan
    Shin, Won Suk
    Shim, Hong-Ku
    Moon, Sang-Jin
    MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 2010, 520 : 286 - 294
  • [8] Synthesis of new conjugated thiophene polymers
    Cervini, R
    Holmes, AB
    Moratti, SC
    Kohler, A
    Friend, RH
    SYNTHETIC METALS, 1996, 76 (1-3) : 169 - 171
  • [9] Synthesis and photophysical properties of conjugated polymers with pendant 9,10-anthraquinone units
    Gomez, Rafael
    Blanco, Raul
    Veldman, Dirk
    Segura, Jose L.
    Janssen, Rene A. J.
    JOURNAL OF PHYSICAL CHEMISTRY B, 2008, 112 (16): : 4953 - 4960
  • [10] Conjugated Polymers with Pendant Iniferter Units: Versatile Materials for Grafting
    Ivanova-Mitseva, Petya K.
    Fragkou, Vasiliki
    Lakshmi, Dhana
    Whitcombe, Michael J.
    Davis, Frank
    Guerreiro, Antonio
    Crayston, Joseph A.
    Ivanova, Diana K.
    Mitsev, Petar A.
    Piletska, Elena V.
    Piletsky, Sergey A.
    MACROMOLECULES, 2011, 44 (07) : 1856 - 1865
12345