A convenient synthesis of phosphorodithioates and novel conversion of epoxides to thiiranes

被引：24

作者：

Kaboudin, B ^{[1
]}

Norouzi, H ^{[1
]}

机构：

[1] IASBS, Dept Chem, Gava Zang 45195159, Zanjan, Iran

来源：

SYNTHESIS-STUTTGART | 2004年 / 12期

关键词：

phosphorodithioates; alumina; epoxides; thiiranes; microwave;

D O I：

10.1055/s-2004-829176

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Alumina-supported ammonium acetate under microwave irradiation was found to be an efficient reagent for the preparation of phosphorodithioates from phosphorus pentasulfide under solvent-free condition. A simple, efficient, and new method has been developed for the synthesis of thiiranes from epoxides through a one-pot reaction of epoxides with the mixture of phosphorus pentasulfide in the presence of ammonium acetate and acidic alumina under reflux in EtOH or solvent-free conditions under microwave irradiation. These methods are easy, rapid, and good-yielding reactions for the synthesis of phosphorodithioates and thiiranes.

引用

页码：2035 / 2039

页数：5

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