Thermolysis of salts of [ReCl6]2- and [ReBr6]2- anions

被引：0

作者：

Gubanov, AI ^{[1
]}

Korenev, SV ^{[1
]}

Gromilov, SA ^{[1
]}

Shubin, YV ^{[1
]}

机构：

[1] Russian Acad Sci, Inst Inorgan Chem, Siberian Div, Novosibirsk 630090, Russia

来源：

RUSSIAN JOURNAL OF INORGANIC CHEMISTRY | 2003年 / 48卷 / 03期

关键词：

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Thermolysis of [Pd(NH3)(4)] [ReHal(6)], [Pt(NH3)(4)] [ReHal(6)], and (NH4)(2)[ReHal(6)], where Hal = Cl or Br, has been studied under an inert atmosphere. Several tendencies in thermolysis have been found. Two-phase systems containing two solid solutions, one based on the fcc cell of platinum (palladium) and the other based on the hcp cell of rhenium, are the final thermolysis products of the double complexes under an inert atmosphere. Reducing the complexes under a hydrogen atmosphere can yield single-phase palladium-rhenium solid solutions.

引用

页码：342 / 346

页数：5

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