Catalytic carbon-chlorine bond cleavage via electrochemical reduction of [ReCl6]2-

被引：3

作者：

Brown, AR ^{[1
]}

Taylor, KJ ^{[1
]}

Yellowlees, LJ ^{[1
]}

机构：

[1] Univ Edinburgh, Dept Chem, Edinburgh EH9 3JJ, Midlothian, Scotland

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1998年 / 14期

关键词：

D O I：

10.1039/a802888e

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Electrochemical reduction of hexachlororhenate(Iv) in chlorinated solvents gave rise to a catalytic cycle producing free chloride and radical dimerisation products. Chlorine-36 tracer experiments showed this free chloride to be derived not from the solvent, as would be expected for a classical redox catalysis, but from the metal complex. A co-ordinatively unsaturated rhenium(III) intermediate capable of abstracting chlorine atoms to regenerate the starting material is proposed as the reactive species.

引用

页码：2401 / 2404

页数：4

共 50 条

[1] CATALYTIC ELECTROCHEMICAL REDUCTION OF CARBON-CHLORINE BOND
SEASE, JW
REED, RC
[J]. TETRAHEDRON LETTERS, 1975, (06) : 393 - 396
[2] Carbon-chlorine and carbon-bromine bond cleavage in the catalytic hydrodehalogenation of halogenated aromatics
Park, C
Menini, C
Valverde, JL
Keane, MA
[J]. JOURNAL OF CATALYSIS, 2002, 211 (02) : 451 - 463
[3] Carbon-chlorine bond cleavage in chlorofluoroethanes on Pd(111)
Chan, CW
Gellman, AJ
[J]. CATALYSIS LETTERS, 1998, 53 (3-4) : 139 - 143
[4] Ab initio study of carbon-chlorine bond cleavage in carbon tetrachloride
Zhang, NL
Blowers, P
Farrell, J
[J]. ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2005, 39 (02) : 612 - 617
[5] Thermolysis of salts of [ReCl6]2- and [ReBr6]2- anions
Gubanov, AI
Korenev, SV
Gromilov, SA
Shubin, YV
[J]. RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2003, 48 (03) : 342 - 346
[6] Electrochemical reductive cleavage of carbon-chlorine bond in 1-chloro-2,4-dinitrobenzene
Prasad, MA
Sangaranarayanan, MV
[J]. ELECTROCHIMICA ACTA, 2005, 51 (02) : 242 - 246
[7] Catalytic Carbon-Chlorine Bond Activation by Selenium-Based Chalcogen Bond Donors
Wonner, Patrick
Vogel, Lukas
Kniep, Florian
Huber, Stefan M.
[J]. CHEMISTRY-A EUROPEAN JOURNAL, 2017, 23 (67) : 16972 - 16975
[8] A new proposed mechanism for the cathodic reduction of a carbon-chlorine bond in 2-acetylphenyltrichloroacetate
Batanero, B
Barba, F
[J]. ELECTROCHEMISTRY COMMUNICATIONS, 2001, 3 (11) : 595 - 598
[9] Formation of N-acetyl-2,3-dihydroindoles by the electrochemical cleavage of the carbon-chlorine bond in N-allyl-2-chloroacetanilides
Dias, M
Gibson, M
Grimshaw, J
Hill, I
Trocha-Grimshaw, J
Hammerich, O
[J]. ACTA CHEMICA SCANDINAVICA, 1998, 52 (05): : 549 - 554
[10] SELECTIVE PHOTOCHEMICAL REDUCTION OF CARBON-CHLORINE BOND IN FLUOROPROPANOATES AND ITS QUANTUM YIELDS
PALETA, O
JEZEK, R
DEDEK, V
[J]. COLLECTION OF CZECHOSLOVAK CHEMICAL COMMUNICATIONS, 1983, 48 (03) : 766 - 771

← 1 2 3 4 5 →