Crystal structure, magnetic and photoelectric properties of coordination polymer [Co2(C3H4N2)4(C10H2O8)]n

被引：4
|
作者：
Niu, SY [1 ]
Fan, HT
Jin, J
Jin, XL
Yang, ZZ
机构：
[1] Liaoning Normal Univ, Dept Chem, Dalian 116029, Peoples R China
[2] Beijing Univ, Dept Chem, Beijing 100871, Peoples R China
来源：
CHINESE SCIENCE BULLETIN | 2004年 / 49卷 / 17期
基金：
中国国家自然科学基金;
关键词：
Co(II) coordination polymer; solvothermal synthesis; crystal structure; magnetism; photoelectric property;
D O I：
10.1360/04wb0012
中图分类号：
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号：
07 ; 0710 ; 09 ;
摘要：
A novel Co(II) coordination polymer bridged by 1,2,4,5-benzene-tetracarboxylate is solvothermally synthesized, which possesses one-dimensional chain structure. The complex crystallizes in the triclinic crystal system, P (1) over bar space group, a = 0.9610(1) not, b = 0.9684(1) not, c = 0.7924(1) nm, alpha = 96.695(9)degrees, beta = 102.741(6)degrees, gamma = 116.551(5)degrees, V = 0.6236(2) nm(3), Z = 2, R-1 = 0.0342, wR(2) = 0.0990. The surface photovoltage spectra measurement shows that the title complex exhibits obvious photovoltage response in the 300-800 nm regions. The variable temperature susceptibility reveals that the complex possesses weak antiferromagnetic property.
引用
收藏
页码：1812 / 1815
页数：4
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