Solid-Supported Palladium Catalysts in Sonogashira Reactions: Recent Developments

被引：54
|
作者：
Alonso, Diego A.
Baeza, Alejandro
Chinchilla, Rafael [1 ]
Gomez, Cecilia
Guillena, Gabriela
Pastor, Isidro M. [1 ]
Ramon, Diego J.
机构：
[1] Univ Alicante, Fac Sci, Dept Organ Chem, POB 99, E-03080 Alicante, Spain
来源：
CATALYSTS | 2018年 / 8卷 / 05期
关键词：
palladium; catalysis; Sonogashira reaction; supported reagents; cross-coupling reactions; COPPER-FREE SONOGASHIRA; EFFICIENT HETEROGENEOUS CATALYST; CROSS-COUPLING REACTIONS; N-HETEROCYCLIC CARBENE; WALLED CARBON NANOTUBES; HIGHLY-ACTIVE CATALYST; C BOND FORMATION; SUZUKI-MIYAURA; POLYSTYRENE RESIN; LIGAND-FREE;
D O I：
10.3390/catal8050202
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The Sonogashira cross-coupling reaction is the most frequently employed synthetic procedure for the preparation of arylated alkynes, which are important conjugated compounds with multiple applications. Despite of their rather high price, this reaction is usually catalyzed by palladium species, making the recovery and reuse of the catalyst an interesting topic, mainly for industrial purposes. Easy recycle can be achieved anchoring the palladium catalyst to a separable support. This review shows recent developments in the use of palladium species anchored to different solid supports as recoverable catalysts for Sonogashira cross-coupling reactions.
引用
下载
收藏
页数：39
相关论文
共 50 条
  • [41] Eosin Y: Homogeneous Photocatalytic In-Flow Reactions and Solid-Supported Catalysts for In-Batch Synthetic Transformations
    Herbrik, Fabian
    Camarero Gonzalez, Patricia
    Krstic, Milena
    Puglisi, Alessandra
    Benaglia, Maurizio
    Sanz, Miguel A.
    Rossi, Sergio
    APPLIED SCIENCES-BASEL, 2020, 10 (16):
  • [42] Copper- and palladium-containing perovskites: Catalysts for the Ullmann and Sonogashira reactions
    Lohmann, S
    Andrews, SP
    Burke, BJ
    Smith, MD
    Attfield, JP
    Tanaka, H
    Kaneko, K
    Ley, SV
    SYNLETT, 2005, (08) : 1291 - 1295
  • [43] Solid-Supported Synthesis of Glycoconjugates
    Lonnberg, Harri
    CURRENT ORGANIC SYNTHESIS, 2009, 6 (04) : 400 - 425
  • [44] A Solid-Supported Organocatalyst for Continuous-Flow Enantioselective Aldol Reactions
    Ayats, Carles
    Henseler, Andrea H.
    Pericas, Miquel A.
    CHEMSUSCHEM, 2012, 5 (02) : 320 - 325
  • [45] Synthesis, analysis, and utility of green, solid-supported palladium-NHC complexes
    Cyr, Noah
    Johnson, Reece
    Paull, Daniel
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2019, 257
  • [46] Palladium-Catalyzed Cross-Coupling Reactions of Arylsiloxanes with Aryl Halides: Application to Solid-Supported Organic Synthesis
    Traficante, Carla I.
    Delpiccolo, Carina M. L.
    Mata, Ernesto G.
    ACS COMBINATORIAL SCIENCE, 2014, 16 (05) : 211 - 214
  • [47] Synthesis and cross-coupling reactions of solid-supported alkylzinc reagents
    Jackson, RFW
    Oates, LJ
    Block, MH
    CHEMICAL COMMUNICATIONS, 2000, (15) : 1401 - 1402
  • [48] SOLID-SUPPORTED LIGATION PRIMER
    POCHET, S
    ARCANGIOLI, B
    TAM, HD
    NUCLEIC ACIDS RESEARCH, 1988, 16 (04) : 1619 - 1619
  • [49] Sonogashira coupling:: silica supported aqueous phase palladium catalysts versus their homogeneous analogs
    Quignard, F
    Larbot, S
    Goutodier, S
    Choplin, A
    JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2002, (06): : 1147 - 1152
  • [50] Recent developments in palladium-catalyzed coupling reactions
    van de Weghe, P
    LETTERS IN ORGANIC CHEMISTRY, 2005, 2 (02) : 113 - 117
12345