Zwitterionic ferrocenyldithiophosphonates:: the molecular structure of [FcP(S)S(OCH2CH2NH2Me)] [Fc = Fe(η5-C5H4)(η5-C5H5)]

被引：13

作者：

Karakus, M ^{[1
]}

Lönnecke, P

Hey-Hawkins, E

机构：

[1] Pamukkale Univ, Fac Arts & Sci, Dept Chem, TR-20017 Denizli, Turkey

[2] Univ Leipzig, Inst Anorgan Chem, D-04103 Leipzig, Germany

来源：

POLYHEDRON | 2004年 / 23卷 / 14期

关键词：

zwitterionic ferrocenyldithiophosphonates; molecular structures;

D O I：

10.1016/j.poly.2004.07.003

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Ferrocenyldithiodiphosphetane [FcPS(mu-S)](2) [Fc = Fe(eta(5)-C5H4)(eta(5)-C5H5)] reacts with the aminoethanol derivatives HOCH2CH2NHMe and HOCH2CH2NEt2 to give the first structurally characterised examples of zwitterionic (O-ethylammonium)ferrocenyldithiophosphonates, [FcP(S)S((OCH2CH2NHRR2)-R-1)] (R-1 = H, R-2 = Me (1); R-1 = R-2 = Et (2)). 1 and 2 were characterised by elemental analyses, IR, NMR spectroscopy (H-1, C-13 (for 2) and P-31) and mass spectrometry. A crystal structure determination was carried out on 1. (C) 2004 Elsevier Ltd. All rights reserved.

引用

页码：2281 / 2284

页数：4

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