Direct coupling reaction between alcohols and allyltrimethylsilane catalyzed by phosphomolybdic acid

被引：14
|
作者：
Kadam, Santosh T. [1 ]
Lee, Hanbin [1 ]
Kim, Sung Soo [1 ]
机构：
[1] Inha Univ, Dept Chem, Inchon 402751, South Korea
来源：
APPLIED ORGANOMETALLIC CHEMISTRY | 2010年 / 24卷 / 02期
关键词：
allylation; alcohols; allyltrimethylsilane; PMA; EFFICIENT CATALYST; BENZYLIC ALCOHOLS; ALLYLATION; KETONES; CYANOSILYLATION;
D O I：
10.1002/aoc.1527
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
Phosphomolybdic acid (PMA) is a simple and efficient catalyst for direct coupling reaction of alcohols with allyltrimethylsilane. Direct nucleophilic allylation of alcohol with allyltrimethylsilane proceeds in considerably good yield in the presence of catalytic amount of (0.5 mol %) PMA at room temperature. Copyright (C) 2009 John Wiley & Sons, Ltd.
引用
收藏
页码：67 / 70
页数：4
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