Ion-exchange processes M(II) → Fe(III) and Fe(III) → M(II) in metal hexacyanoferrate(II) gelatin-immobilized matrices (M = Mn, Co, Ni, Cu, Zn, Cd)

被引：7

作者：

Mikhailov, OV

Tatarintseva, TB

Naumkina, NI

Lygina, TZ

机构：

[1] Kazan State Power Engn Univ, Kazan, Tatarstan, Russia

[2] Cent Res Inst Nanomet Mineral Geol, Kazan, Tatarstan, Russia

来源：

RUSSIAN JOURNAL OF COORDINATION CHEMISTRY | 2004年 / 30卷 / 09期

关键词：

D O I：

10.1023/B:RUCO.0000040724.53882.90

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Ion-exchange reactions M2+ --> Fe3+ and Fe3+ --> M2+ (M = Mn, Co, Ni, Cu, Zn, Cd) were studied in metal(II) hexacyanoferrate(II) gelatin-immobilized matrices M-2[Fe(CN)(6)] in contact with aqueous FeCl3 solutions and Fe-4[Fe(CN)(6)](3) in contact with a ueous MCl2 solutions. It was shown that in both cases, M2+ was replaced by Fe3+ and Fe3+ was replaced by M2+ to some extent, but no complete replacement was observed in the M-2[Fe(CN)(6)]-FeCl3 or Fe-4[Fe(CN)(6)](3)-MCl2 systems under study. No electrophilic substitution Fe3+ Mn2+ was found to occur in any noticeable degree during the contact of Fe-4[Fe(CN)(6)](3) with aqueous MnCl2 solutions even when this contact occurred for 1 h and longer.

引用

页码：639 / 647

页数：9

共 50 条

[41] EXTRACTION OF MN(II), FE(III), CO(II), NI, CU AND ZN WITH TRI-N-OCTYLAMINE, AND SEPARATION OF FE, ZN, CO AND NI
NAKAGAWA, G
NIPPON KAGAKU ZASSHI, 1961, 82 (08): : 1042 - &
[42] VO(II), MN(II), FE(III), CO(II), NI(II), CU(II), ZN(II), CD(II), HG(II), RU(III), RH(III), PD(II), PT(IV) AND AU(III) COMPLEXES OF BENZIDINE
RAHMAN, SMF
AHMAD, N
KUMAR, V
INDIAN JOURNAL OF CHEMISTRY, 1975, 13 (01): : 86 - 88
[43] Synthesis and characterization of p-dimethylaminobenzaldehyde complexes of Cr(III), Mn(II), Fe(III), Co(II), Ni(II), Cu(II) and Zn(II)
Yazicilar, TK
Yilmaz, VT
Olmez, H
SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY, 1997, 27 (06): : 825 - 833
[44] STUDIES ON PURIFICATION OF CADMIUM SALT FROM FE(III), IN(III), CU(II), PB(II), ZN(II), CO(II), NI(II) AND MN(II) ON CHELATING ION-EXCHANGERS
HUBICKI, Z
HUNGARIAN JOURNAL OF INDUSTRIAL CHEMISTRY, 1988, 16 (02): : 217 - 225
[45] Catalytic hydroxylation of phenol over CuM(II)M(III) ternary hydrotalcites, where M(II) = Ni or Co and M(III) = Al, Cr or Fe
Dubey, A
Kannan, S
Velu, S
Suzuki, K
APPLIED CATALYSIS A-GENERAL, 2003, 238 (02) : 319 - 326
[46] CHROMATOGRAPHIC SEPARATIONS OF MN(II), FE(III), CO(II), NI(II), CU(II) AND ZN(II), 3D-TRANSITION METAL IONS ON CATION EXCHANGE PAPERS
DE, AK
SARKAR, SK
BHATTACH.CR
INDIAN JOURNAL OF CHEMISTRY, 1971, 9 (08): : 876 - &
[47] Complexation of Co(III) with dithiooxamide and its N,N′-diphenyl derivative on cobalt(III) hexacyanoferrate(II) gelatin-immobilized matrices
Mikhailov, OV
ZHURNAL NEORGANICHESKOI KHIMII, 1997, 42 (08): : 1312 - 1320
[48] Physically Crosslinked Chondroitin Sulfate (CS)-Metal Ion (M: Fe(III), Gd(III), Zn(II), and Cu(II)) Particles for Versatile Applications and Their Biosafety
Suner, Selin S.
Sahiner, Mehtap
Umut, Evrim
Ayyala, Ramesh S.
Sahiner, Nurettin
PHARMACEUTICALS, 2023, 16 (04)
[49] DOUBLE SULFATES OF M(II) WITH ETHANOLAMMONIUM (WHERE M IS MN, CO, NI, CU, ZN OR CD)
JORDANOVSKA, V
TROJKO, R
THERMOCHIMICA ACTA, 1993, 228 : 231 - 240
[50] ON THE ORTHO-POSITRONIUM QUENCHING REACTIONS PROMOTED BY FE(II), FE(III), CO(III), NI(II), ZN(II) AND CD(II) CYANOCOMPLEXES
LAZZARINI, ALF
LAZZARINI, E
RADIATION PHYSICS AND CHEMISTRY, 1990, 36 (03): : 377 - 381

← 1 2 3 4 5 →