O,O′-Ditolyldithiophosphates of Zinc(II), Cadmium(II) and Mercury(II)

被引：0
|
作者：
Kour, Simerpal [1 ]
Gupta, Bhawana [1 ]
Chander, Romesh [1 ]
Pandey, Sushil Kumar [1 ]
机构：
[1] Univ Jammu, Dept Chem, Jammu 180006, Jammu & Kashmir, India
来源：
MAIN GROUP METAL CHEMISTRY | 2009年 / 32卷 / 04期
关键词：
Metallo-organic; Phosphorus compounds; Ditolyldithiophosphates; Dialkyl-/alkylenedithiophosphates; CRYSTAL-STRUCTURE; DITHIOPHOSPHATE; DERIVATIVES; CHEMISTRY; DIALKYL; P-31;
D O I：
暂无
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
O,O'-Ditolyldithiophosphato complexes of zinc(II), cadmium(II) and mercury(II) corresponding to [(CreO)(2)PS2](2)M (CreO = o-, m- and p-CH3C6H4 and M = Zn, Cd and Hg) have been synthesized by the reaction of metal dichlorides, MCl2, with triethylammonium O,O'-ditolylphosphorodithioate, (o-, m- and p-CH3C6H4O)(2)PS2HNEt3, in 1:2 molar stoichiometry tinder anhydrous conditions These complexes were characterized by elemental analyses, molecular weight determination, IR and NMR (H-1, C-13 and P-31) spectral studies, which revealed monomeric nature of these complexes and the metal atom being four-coordinatively bonded to two bidentate dithiophosphate ligands, leading to a square plannar geometry around the metal atom
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页码：195 / 202
页数：8
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