Catalytic properties of supported cobalt catalysts for steam reforming of ethanol

被引:229
|
作者
Haga, F [1 ]
Nakajima, T [1 ]
Miya, H [1 ]
Mishima, S [1 ]
机构
[1] Shinshu Univ, Fac Engn, Dept Chem & Mat Engn, Nagano 380, Japan
关键词
steam reforming of ethanol; Co/Al2O3; supported cobalt catalysts; OXIDE CATALYST; ACETONE; CONVERSION;
D O I
10.1023/A:1019039407126
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Steam reforming of ethanol, C2H5OH + H2O --> 2CO + 4H(2), was carried out over Co/Al2O3, Co/SiO2, Co/MgO, Co/ZrO2 and Co IC. The properties of the Co catalysts were greatly affected by the supports. Co/Al2O3 exhibited the highest selectivity for steam reforming of ethanol by suppression of methanation of CO and decomposition of ethanol.
引用
收藏
页码:223 / 227
页数:5
相关论文
共 50 条
  • [41] Support and alloy effects on activity and product selectivity for ethanol steam reforming over supported nickel cobalt catalysts
    Chen, Luwei
    Choong, Catherine Kai Shin
    Zhong, Ziyi
    Huang, Lin
    Wang, Zhan
    Lin, Jianyi
    INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2012, 37 (21) : 16321 - 16332
  • [42] The Effect of Surface Acidic and Basic Properties on the Performance of Cobalt-Based Catalysts for Ethanol Steam Reforming
    Song, Hua
    Zhang, Lingzhi
    Ozkan, Umit S.
    TOPICS IN CATALYSIS, 2012, 55 (19-20) : 1324 - 1331
  • [43] The Effect of Surface Acidic and Basic Properties on the Performance of Cobalt-Based Catalysts for Ethanol Steam Reforming
    Hua Song
    Lingzhi Zhang
    Umit S. Ozkan
    Topics in Catalysis, 2012, 55 : 1324 - 1331
  • [44] SYNTHESIS AND USE OF COBALT CATALYSTS FOR HYDROGEN PRODUCTION BY OXIDATIVE STEAM REFORMING OF ETHANOL
    Munoz, Monica
    Espitia, Mauricio
    Moreno, Sonia
    Molina, Rafael
    REVISTA DE INVESTIGACIONES-UNIVERSIDAD DEL QUINDIO, 2013, 24 (01): : 118 - 128
  • [45] Effect of niobia addition on cobalt catalysts supported on alumina for glycerol steam reforming
    Menezes, Joao Paulo da S. Q.
    Duarte, Karine R.
    Manfro, Robinson L.
    Souza, Mariana M. V. M.
    RENEWABLE ENERGY, 2020, 148 : 864 - 875
  • [46] Silica and zirconia supported catalysts for the low-temperature ethanol steam reforming
    Rossetti, Ilenia
    Lasso, Jose
    Nichele, Valentina
    Signoretto, Michela
    Finocchio, Elisabetta
    Ramis, Gianguido
    Di Michele, Alessandro
    APPLIED CATALYSIS B-ENVIRONMENTAL, 2014, 150 : 257 - 267
  • [47] Catalytic monoliths for ethanol steam reforming
    Casanovas, Albert
    de Leitenburg, Carla
    Trovarelli, Alessandro
    Llorca, Jordi
    CATALYSIS TODAY, 2008, 138 (3-4) : 187 - 192
  • [48] Oxidative steam reforming of ethanol over carbon nanofiber supported Co catalysts
    da Silva, Andre L. M.
    Mattos, Lisiane V.
    den Breejen, Johan P.
    Bitter, Johannes H.
    de Jong, Krijn P.
    Noronha, Fabio B.
    CATALYSIS TODAY, 2011, 164 (01) : 262 - 267
  • [49] Low Temperature Steam Reforming of Ethanol Over Supported Noble Metal Catalysts
    Aristides C. Basagiannis
    Paraskevi Panagiotopoulou
    Xenophon E. Verykios
    Topics in Catalysis, 2008, 51 : 2 - 12
  • [50] Glycerol steam reforming over calcium hydroxyapatite supported cobalt and cobalt-cerium catalysts
    J.Dobosz
    M.Cichy
    M.Zawadzki
    T.Borowiecki
    Journal of Energy Chemistry , 2018, (02) : 404 - 412