Conjugated energetic salts based on 3,3′-((1E,1′E)-(2,4,6-trinitro-1,3-phenylene)bis(ethene-2,1-diyl))bis(2,4,6-trinitrophenol)

被引：9

作者：

Xu, Junhui ^{[1
]}

Wei, Jianping ^{[1
]}

Li, Fangmei ^{[1
]}

Ma, Qingguo ^{[1
]}

Peng, Xinhua ^{[1
]}

机构：

[1] Nanjing Univ Sci & Technol, Sch Chem Engn, Nanjing 210094, Jiangsu, Peoples R China

来源：

NEW JOURNAL OF CHEMISTRY | 2014年 / 38卷 / 11期

关键词：

NITROGEN-RICH SALTS; HIGH-PERFORMANCE; SELECTIVE NITRATION; PREDICTION; OXYGEN; THERMOLYSIS; DERIVATIVES; TOLUENE; THERMODYNAMICS; CHLOROBENZENE;

D O I：

10.1039/c4nj01091d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Based on a design strategy that has resulted in conjugated energetic materials, 3,3'-((1E,1'E)-(2,4,6-trinitro-1,3-phenylene)bis(ethane-2,1-diyl))bis(2,4,6-trinitrophenol) and its nitrogen-rich salts were obtained and characterized via spectral and elemental analyses. These new molecules exhibit good thermal stability (T-d = 268.4-311.3 degrees C), especially for hydrazinium salt 4c, which is comparable to that of the benchmark HNS. Also, they exhibit low impact sensitivity (>40 J), high density (1.67-1.88 g cm(-3)), acceptable detonation properties (7268-8527 m s(-1), 26.7-34.1 GPa) and brisance parameters (103.9-144.4). The energetic properties of the salts suggest potential applications to new energetic materials.

引用

页码：5303 / 5311

页数：9

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